2008
DOI: 10.1007/s00216-008-2112-y
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Use of polyurethane foam and 3-hydroxy-7,8-benzo-1,2,3,4-tetrahydroquinoline for determination of nitrite by diffuse reflectance spectroscopy and colorimetry

Abstract: Polyurethane foam (PUF) has been suggested as a solid polymeric reagent for determination of nitrite. The determination is based on the diazotization of end toluidine groups of PUF with nitrite in acidic medium followed by coupling of polymeric diazonium cation with 3-hydroxy-7,8-benzo-1,2,3,4-tetrahydroquinoline. The intensely colored polymeric azodye formed in this reaction can be used as a convenient analytic form for the determination of nitrite by diffuse reflectance spectroscopy (c (min) = 0.7 ng mL(-1))… Show more

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Cited by 17 publications
(6 citation statements)
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“…The underlying principles of reflectance and image acquisition on a scanner are essentially the same. The reflectance on any surface at any given wavelength defines the image, and the colors, acquired on the scanner, and such images are analytically related to the chemical composition defining the colors in the image. , Analysis of the digital image through the analysis of the color, and color matching systems, are very well established in the paint, coatings, and printing industries. Color spaces CMYK, RGB, L *a * b *, and HLS are the best-known systems for numeric representation of color.…”
Section: Resultsmentioning
confidence: 99%
“…The underlying principles of reflectance and image acquisition on a scanner are essentially the same. The reflectance on any surface at any given wavelength defines the image, and the colors, acquired on the scanner, and such images are analytically related to the chemical composition defining the colors in the image. , Analysis of the digital image through the analysis of the color, and color matching systems, are very well established in the paint, coatings, and printing industries. Color spaces CMYK, RGB, L *a * b *, and HLS are the best-known systems for numeric representation of color.…”
Section: Resultsmentioning
confidence: 99%
“…Spectrophotometric nitrite analyses are based on the analysis method developed by Griess and Ilosvay in 1941. The main aim of this method is measurement of wave length of azo-dye which is formed by the reaction of 1-naphthylamine with diazonium salt, formed by the reaction of sulphanilic acid with nitrous acid (Figure 2A) [43]. This orange-red colored compound gives maximum absorbance value at 520 nm wave length.…”
Section: Traditional Methods Used In the Determination Of Nitritementioning
confidence: 99%
“…For example, they successfully quantified adsorbed elements and organic compounds on polyurethane foam with comparable results to traditional adsorption-spectrophotometric methods. [58][59][60] Also, flatbed scanners have been used in conjunction with colorimetric assays for pH monitoring, 61,62 and to develop a dopamine biosensor. 63,64 Another emerging application is scanner based digitization of paper based, inkjet printed, microfluidic devices to perform chemical sensing 65 and immunochemistry.…”
Section: Colorimetric Assaysmentioning
confidence: 99%