2009
DOI: 10.1002/app.31172
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Vanadium(V)/mandelic acid initiated graft copolymerization of acrylamide onto guar gum in an aqueous medium

Abstract: ABSTRACT:The graft copolymerization reaction of acrylamide onto guar gum with a vanadium(V)/mandelic acid redox pair was carried out in an N 2 atmosphere. The optimum concentrations of vanadium(V), mandelic acid, hydrogen ions, acrylamide, and guar gum for the maximum percentage of grafting were 6.0 Â 10 À3 , 2.0 Â 10 À2 , 55.0 Â 10 À2 , and 20.0 Â 10 À2 mol/dm 3 and 110.1 Â 10 À2 g/dm 3 , respectively. The optimum time and temperature of reaction were 90 min and 35 C, respectively, and during the study of [H … Show more

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Cited by 19 publications
(7 citation statements)
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“…The degree of swelling at time t ( Q t ) was estimated in grams of water per gram of dry hydrogel with the following equation: Qt = mtm0m0 where m 0 is the initial weight of the dried disc, namely, the weight at t = 0; m t is the weight after time t; and Q t is the weight of water intake at time t . The equilibrium swelling ( Q ∞ ) was calculated with the following formula: Q = mtm0m0 …”
Section: Methodsmentioning
confidence: 99%
“…The degree of swelling at time t ( Q t ) was estimated in grams of water per gram of dry hydrogel with the following equation: Qt = mtm0m0 where m 0 is the initial weight of the dried disc, namely, the weight at t = 0; m t is the weight after time t; and Q t is the weight of water intake at time t . The equilibrium swelling ( Q ∞ ) was calculated with the following formula: Q = mtm0m0 …”
Section: Methodsmentioning
confidence: 99%
“…Linear polymers are known to have a higher viscosity as compared with their branched counterparts with the same molecular weight. The reason for this is that linear polymers have a higher hydrodynamic volume in solution; the longer the chain, higher the intrinsic viscosity and vice versa 49. It is also known that [η] depends on some key parameters including temperature15 and solvent interactions 50, 51.…”
Section: Resultsmentioning
confidence: 99%
“…The graft degree on the modified membrane surfaces was calculated through the grafting yield (GD, %), based on the difference in the dried membrane weights before and after surface grafting, over the membrane surface area. GD = true{true[true(m1 motrue)/motrue]×100true}true(%true) where m o and m 1 are the weights of the dried membrane sample before and after grafting, respectively.…”
Section: Methodsmentioning
confidence: 99%