Despite the recent upsurge in research on GaSb-based systems, only few systematic investigations have been performed on the fundamental optical and electronic properties of Al x Ga 1Ϫx Sb/GaSb quantum wells. For this reason we studied a series of Al 0.4 Ga 0.6 Sb/GaSb single quantum wells, with well thicknesses ranging from 40 to 117 Å, by reflectance ͑R͒ and photoreflectance ͑PR͒ in the 0.6 to 1.5 eV spectral range and at temperatures from 6 to 300 K. The structures were grown by molecular-beam epitaxy on ͑001͒ GaSb substrates and structurally and compositionally characterized by photoluminescence, x-ray diffraction, and reflection highenergy electron diffraction. Both R and PR spectra showed clear evidence of the structures associated with the transitions allowed between the nth heavy-͑light-͒ hole subband and the nth conduction subband for nϭ1 and 2. Standard critical-point line shapes fitted satisfactorily the PR structures, allowing accurate determination of both transition energies and broadening parameters as functions of the well thickness. The transition energies were well fitted by a theoretical model based on the envelope-function scheme, thus giving reliable values for the two fit parameters, i.e., the band offset and the conduction-band nonparabolicity. ͓S0163-1829͑99͒05423-5͔ PHYSICAL REVIEW B 15 JUNE 1999-I VOLUME 59, NUMBER 23 PRB 59 0163-1829/99/59͑23͒/15395͑7͒/$15.00 15 395