Vivianite formation as indicator of human impact in porous sediments

Abstract

Environmental geological survey of a chemical works situated in NE Hungary has been performed for decades. Up till now, several hundreds of drillings of different depths as well as engineering geological soundings have been carried out in the area. Vivianite has been found in a discrete part of a drilling in a gray, silty bed at the depth 6.8–8.5 m. Vivianite was analyzed using X-ray powder diffraction (XRPD), thermal analysis (TG/DTG), and scanning electron microscopic and energy dispersive spectrometry (SEM–EDS) techniques. To demonstrate the spatial distribution of hydrochemical parameters and selected chemical constituents the available data concerning drillings and hydrochemical analyses were collected and evaluated, and field measurements were also performed. For mapping the distribution of relevant physico-chemical parameters and chemical constituents kriging interpolation method was used. Archive aerial photographs demonstrate that a coffered, earth-bedded reservoir for storing huge amounts of extracted plant debris is situated in the vicinity of the drilling. Our study suggests that orthophosphate derived from decomposing biomass entered the groundwater and accumulated within the lowest permeability zone of the intact bedrock. Therefore, the discrete appearance of vivianite in the drilling can be regarded, at least partly, the result of a man-induced mineralogical process.

Unravelling key factors controlling vivianite formation during anaerobic digestion of waste activated sludge

“…Vivianite (Fe 3 (PO 4 ) 2 ⋅8H 2 O) is a remarkably stable ferrophosphorus compound (Tessadri et al, 2000), and common in anaerobic environments rich in iron and phosphorous, such as soils and deep lake sediments ( Árpád et al, 2021;Rothe et al, 2016;Wu et al, 2019). Vivianite has also been found in pipelines (Prot et al, 2021) and WAS in WWTPs (Wilfert et al, 2016;Wu et al, 2019) and accounts for a majority of phosphorous and iron in anaerobic digestion (AD) of WAS (Wilfert et al, 2018).…”