Water-assisted proton conductivity of two lanthanide-based supramolecules

Abstract

By using a multifunctional organic ligand, 2-(3-benzoylthioureido)ethanoic acid (H3L) and a N-containing ligand, 1,10-phenanthroline (Phen) and two kinds of lanthanides (Gd(III) and Ho(III)), two binuclear supramolecules, [Gd2(2-H2L)2(H2L)2(Phen)2(NO3)2(CH3OH)] (1) and [Ho2(2-H2L)2(H2L)2(Phen)2(NO3)2(CH3OH)]...