We are interested in the approximation in Wasserstein distance with index ρ ≥ 1 of a probability measure µ on the real line with finite moment of order ρ by the empirical measure of N deterministic points. The minimal error converges to 0 as N → +∞ and we try to characterize the order associated with this convergence. Apart when µ is a Dirac mass and the error vanishes, the order is not larger than 1. We give a necessary condition and a sufficient condition for the order to be equal to this threshold 1 in terms of the density of the absolutely continuous with respect to the Lebesgue measure part of µ. We also check that for the order to lie in the interval (1/ρ, 1), the support of µ has to be a bounded interval, and that, when µ is compactly supported, the order is not smaller than 1/ρ. Last, we give a necessary and sufficient condition in terms of the tails of µ for the order to be equal to some given value in the interval (0, 1/ρ).