1998
DOI: 10.1016/s1352-2310(98)00097-1
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Weekly and daily precipitation chemistry network comparisons in the eastern U.S. NADP/NTN vs MAP3S/AIRMoN

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Cited by 38 publications
(18 citation statements)
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“…Presuming these losses are primarily due to volatization it is likely that the NH + 4 losses will be lower in MMSF due to the relatively low WD pH. However, it is also worthy of note that the uncertainty is comparable to values reported for coincident samples collected from identical colocated samplers in the NADP network (Nilles et al, 1994), and Butler and Likens (1998) also reported lower concentrations of NH + 4 in weekly samples relative to daily or event based sampling which they attributed to biological processes. Hence, it remains likely that the NH + 4 concentrations (and fluxes) from the Aerochem collected samples may underestimate actual concentrations.…”
mentioning
confidence: 84%
“…Presuming these losses are primarily due to volatization it is likely that the NH + 4 losses will be lower in MMSF due to the relatively low WD pH. However, it is also worthy of note that the uncertainty is comparable to values reported for coincident samples collected from identical colocated samplers in the NADP network (Nilles et al, 1994), and Butler and Likens (1998) also reported lower concentrations of NH + 4 in weekly samples relative to daily or event based sampling which they attributed to biological processes. Hence, it remains likely that the NH + 4 concentrations (and fluxes) from the Aerochem collected samples may underestimate actual concentrations.…”
mentioning
confidence: 84%
“…Butler and Likens (1998) [38] found that daily samples may provide a better estimate of actual rain chemistry than weekly samples. Gilliland et al (2002) [39] .…”
Section: Sample Collectionmentioning
confidence: 99%
“…It has been suggested that lighter falls rich in acidic substances are diluted by any other fall which may occur during the week and thus lead to higher pH values in weekly precipitation samples than event-based samples (Sisterson et al 1985;Tait and Thaler 2000). On the other hand, the continued conversion of dissolved SO 2 to SO 4 2-has been suggested to increase acidity in weekly samples (Bulter and Likens 1998). Thus, the effect of different sampling frequencies on precipitation chemistry is unclear and cannot be used with confidence to explain the decrease in the pH of our weekly precipitation samples.…”
Section: Precipitation Chemistrymentioning
confidence: 99%