1976
DOI: 10.1039/c39760000653
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X-Ray crystal structure of antimony trichloride difluoride

Abstract: An X-ray crystallographic analysis indicates that SbCl,F, exists as a cis-fluorine-bridged tetramer giving a distorted octahedral arrangement of halogen atoms around each antimony atom.

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Cited by 2 publications
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“…The bridges between Sb(1) and Sb(2), and Sb(2) and Sb(3) are both symmetric (meal Sb-1-= 2.08 A) whereas that between SbQ1) and Sb (3) F, (9), and SbC1,F (8) The CI-F disorder has already been discussed in the section concerning the refinement of the structure. The Sb-CI(F) bond length, 2.12 A, is approximately the value expected for a site consisting of 75% chlorine and 25% fluorine.…”
Section: Discussionmentioning
confidence: 99%
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“…The bridges between Sb(1) and Sb(2), and Sb(2) and Sb(3) are both symmetric (meal Sb-1-= 2.08 A) whereas that between SbQ1) and Sb (3) F, (9), and SbC1,F (8) The CI-F disorder has already been discussed in the section concerning the refinement of the structure. The Sb-CI(F) bond length, 2.12 A, is approximately the value expected for a site consisting of 75% chlorine and 25% fluorine.…”
Section: Discussionmentioning
confidence: 99%
“…However, a phase change is thought to occur at low temperatures, resulting in a different structure. Although a number of structures have been postulated (3)(4)(5)(6)(7)(8)(9), Mossbauer evidence at 4 K suggests a trigonal bipyramidal arrangement of chlorine atoms around antimony (6). SbF, (7), SbC1,F (81, and SbC13F, (9) have all been shown by X-ray crystallography to exist as cis fluorinebridged tetramers.…”
Section: Introductionmentioning
confidence: 99%
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