Ferroelectric materials have found extensive application in microelectronics, microelectromechanical systems (MEMS), and electro-optic devices.[1] Ferroelectric oxides have been used in modulators, resonators, piezoelectric components, infrared-detector elements, acoustic delay lines, microwave-tunable devices, and in data processing and memory elements. The use of thin-film layers of such ferroelectric oxides can dramatically reduce device operating voltages and enable monolithic device integration. However, the integration of high-quality ferroelectric thin films in planar device architectures on silicon substrates remains a technological challenge. A promising candidate material for such thin-film integration is LiNbO 3 , a well-known nonlinear optical crystal that exhibits an extraordinary spontaneous polarization (71 lC cm -2). LiNbO 3 optical waveguides are of great importance in electro-optic applications [2,3] and could be substantially improved through a successful thin-film integration technology. Direct wafer bonding and layer-transfer techniques are promising methods for fabricating high-quality single-crystal thin films without heteroepitaxial growth and the attendant materials-defect problems associated with lattice mismatch between the thin-film layer and the silicon substrate. Implantation-induced layer transfer processes have previously been reported for the layer transfer of Si, InP, Ge, and diamond. [4,5] Recently, layer splitting and transfer of ferroelectric materials such as LiNbO 3 , LiTaO 3 , KTaO 3 , SrTiO 3 , and BaTiO 3 have also been demonstrated through a sacrificial wet etching and anodic bonding process combined with a crystal ion slicing method. [6][7][8][9][10][11] However, because of large mismatch in the coefficient of thermal expansion (CTE) between LiNbO 3 ((7.5-14.4) × 10 -6 m°C -1 , depending on cutting orientation) and Si (2.6 × 10 -6 m°C -1 ), thermal mismatch-induced stress at the LiNbO 3 /Si interface occurring during heating and cooling steps in the direct bonding and layer transfer process is quite large in comparison to other material systems. This complicates the development of layer transfer and bonding processes for the integration of LiNbO 3 on silicon.Laser lift off (LLO) and laser-induced forward transfer methods have been widely investigated as an alternative approach to the integration of PZT (Pb(Zr,Ti)O 3 ), GaN, and Si thin films. These methods employ excimer laser irradiation and an intermetallic bonding layer (PdIn) as an adhesive layer. [12][13][14] However, for the microphotonic device applications anticipated in this study, the LiNbO 3 thin film needs to be formed directly on the silicon substrate without any intermediate metallic adhesive layer.In this communication, we introduce a novel method of thin-film integration using laser-induced layer transfer in conjunction with ion implantation to integrate single-crystal LiNbO 3 thin films on silicon substrates. Figure 1 represents the overall process. Light ions such as hydrogen and helium are implanted i...