ZnI2 Catalyzed Reduction of Ketones Under Solvent-Free Conditions

Chen, Ling-Zhen; Peng, Jiajian; Li, Jiayun; Bai, Ying; Hu, Yingqian; Qiu, Huayu; Wu, Hui; Lai, Guoqiao

doi:10.2174/157017808785982248

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2009

2016

Publication Types

Select...

Article3

Other1

Book1

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 6 publications

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Ionic and Organometallic‐Catalyzed Organosilane Reductions

2009

Ionic and Organometallic‐Catalyzed Organosilane Reductions

View full text Add to dashboard Cite

Ionic and Organometallic‐Catalyzed Organosilane Reductions

2009

Ionic and Organometallic‐Catalyzed Organosilane Reductions

View full text Add to dashboard Cite

Non‐Redox‐Metal‐Catalyzed Redox Reactions: Zinc Catalysts

2012

Chemistry An Asian Journal

View full text Add to dashboard Cite

The advantages of zinc catalysts, such as their low toxicity, low cost, and environmentally benignity, are encouraging organic chemists to explore their applications in organic synthesis. As a non-redox metal, zinc catalysts have been investigated in redox reactions over the past few decades. Because of the importance of redox reactions, the interest in zinc catalysts, and the fact that no review on zinc-catalyzed redox reactions has been published, herein, I have collected and summarized the main contributions in this area. This review is divided into two parts: reduction reactions and oxidation reactions.

show abstract

Zinc‐Catalyzed Enantioselective Hydrosilylation of Ketones and Imines under Solvent‐Free Conditions

2016

View full text Add to dashboard Cite

The zinc acetate promoted asymmetric hydrosilylation of various ketones and imines under solvent‐free conditions was examined by using an unprecedented low catalyst loading. Exposure of ketones to 0.05 mol % Zn‐based chiral diamine complex in the presence of triethoxysilane afforded enantioenriched alcohols in excellent yields (up to 98 %) and enantioselectivities (up to 97 % ee). This methodology also allowed for the chemoselective 1,2‐reduction of α,β‐unsaturated ketones and imines.

show abstract

ZnI2 Catalyzed Reduction of Ketones Under Solvent-Free Conditions

Cited by 6 publications

References 0 publications

Ionic and Organometallic‐Catalyzed Organosilane Reductions

Ionic and Organometallic‐Catalyzed Organosilane Reductions

Non‐Redox‐Metal‐Catalyzed Redox Reactions: Zinc Catalysts

Zinc‐Catalyzed Enantioselective Hydrosilylation of Ketones and Imines under Solvent‐Free Conditions

Contact Info

Product

Resources

About