NO x gas, and the study on ZnO-based gas sensors attracted the researchers largely. Hitherto, the researchers have synthesized ZnO with different morphology, including nanorods, [9] nanosheets, [10] nanotubes, [11] nanoparticles, [12] nanoplates, [13] nanofilms, [14] and so forth. [15][16][17][18][19][20][21][22][23][24] The different morphology has the considerable impact on the gas sensing performance of MOS gas sensors. A large number of researches indicated that the doped-ZnO materials showed the better performance. The doping components mainly included SnO 2 , WO 3 , Cr 2 O 3 , Co 3 O 4 , Ni, noble metal, etc. [9][10][11][25][26][27][28][29][30][31][32][33][34] Renitta and Vijayalakshmi [30] fabricated a novel nanowhiskers array of Cr incorporated ZnO on ITO substrate by spray pyrolysis technique, and the material exhibited high sensing response to hydrogen gas at room temperature. Liu et al. [28] synthesized Co 3 O 4 /ZnO nanocomposites by an easy wet-chemistry route, and the obtained nanocomposite showed enhanced gas sensing response (about 46%) to 100 ppm ethanol at 170 °C. Tamaekong et al. [31] successfully produced ZnO nanoparticles doped with 0.2-2 at% Pt by flame spray pyrolysis technique. They found that the 0.2 at% Pt/ZnO sensing film showed the highest sensitivity (2.9%) and the fastest response time (≈10 s) to 1000 ppm CO at 350 °C.WO 3 -based gas sensors were widely studied recent years. Zeng et al. [35] prepared a porous WO 3 sensor by anodic oxidation of DC magnetron sputtered metallic tungsten (W) film on alumina substrate. The prepared WO 3 sensor achieved the maximum response toward NO 2 at a low operating temperature of 150 °C. You et al. [36] successfully synthesized the nanosheets assembled hierarchical WO 3 hollow microspheres by sintering acid-treated CaWO 4 hollow microspheres precursor at 500 °C, and the response to 40 ppb NO 2 was about 16 at 75 °C. Vuong et al. [37] studied the gas sensing mechanism of a 1D highly porous WO 3 nanowire gas sensor, which was based on adsorption-desorption kinetics of oxidizing gases. However, the gas sensing properties of WO 3 /ZnO composite were rarely reported. Tesfamichael et al. [32] prepared W-doped ZnO thin films by magnetron sputtering method. The response time of the W-doped ZnO thin film was 195 s toward 5 ppm NO 2 at 150 °C. Naik et al. [23] synthesized a kind of composite MOS sensor array based on tungsten oxide (WO 3 ) and zinc oxide (ZnO) using a simple mechanical mixing method. The highest response of the composite was 148 toward 800 ppb NO 2 at 300 °C.A kind of novel n-n combined ordered mesoporous WO 3 /ZnO (OM-WO 3 / ZnO) sensor are successfully fabricated in this study. A soft-template method is used to synthesize the ordered mesoporous ZnO matrix. Surfaces of the ZnO matrix are innovatively modified using silane coupling agent (mark as: OM-ZnO-Si), and then a layer of WO 3 film is assembled on the surfaces of the OM-ZnO-Si by chemical plating method for the first time, and the OM-WO 3 /ZnO material is obtained. The prepared OM-WO 3 ...