α-Substitution effect of fluorine atoms in the cobalt-catalyzed hydrosilylation of fluorine-containing aromatic ketones

Kumon, Tatsuya; Sari, Siti Asiah Binti Mohd; Yamada, Shigeyuki; Konno, Tsutomu

doi:10.1016/j.jfluchem.2017.12.003

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Cited by 5 publications

References 59 publications

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Cobalt Complexes Supported by Phosphinoquinoline Ligands for the Catalyzed Hydrosilylation of Carbonyl Compounds

Schiltz

Casaretto

Auffrant

et al. 2022

Chemistry A European J

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P,N phosphinoquinoline based ligands differing by the nature of the phosphorus substituent (iPr, Ph) were employed to synthesize a series of cobalt(II) complexes ([LCoBr2], [L2CoBr](PF6) and [L’2CoBr](PF6)). The latter were obtained in high yield and characterized among others by X‐ray analysis and elemental analysis. Complex [L2CoBr](PF6) showed a very good catalytic activity for the hydrosilylation of various ketones. The catalysis proceeds at a low catalytic loading (1 mol %) with only 1 equivalent of Ph2SiH2 in mild conditions and was efficient with aliphatic or aromatic ketones giving moderate to excellent yields of the corresponding silylated ether.

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Cobalt Complexes Supported by Phosphinoquinoline Ligands for the Catalyzed Hydrosilylation of Carbonyl Compounds

Schiltz

Casaretto

Auffrant

et al. 2022

Chemistry A European J

View full text Add to dashboard Cite

show abstract

Recent advances in catalytic hydrosilylation of carbonyl groups mediated by well-defined first-row late transition metals

Royo

2019

Advances in Organometallic Chemistry

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Earth-abundant metal catalyzed hydrosilylative reduction of various functional groups

Bhunia

Sreejyothi

Mandal

2020

Coordination Chemistry Reviews

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α-Substitution effect of fluorine atoms in the cobalt-catalyzed hydrosilylation of fluorine-containing aromatic ketones

Cited by 5 publications

References 59 publications

Cobalt Complexes Supported by Phosphinoquinoline Ligands for the Catalyzed Hydrosilylation of Carbonyl Compounds

Cobalt Complexes Supported by Phosphinoquinoline Ligands for the Catalyzed Hydrosilylation of Carbonyl Compounds

Recent advances in catalytic hydrosilylation of carbonyl groups mediated by well-defined first-row late transition metals

Earth-abundant metal catalyzed hydrosilylative reduction of various functional groups

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