The production of superlattices with pseudomorphically strained quantum wells (QWs) {InxGa1–xAs/GaAs} grown by molecular beam epitaxy on GaAs substrates with (100), (110), and (111)A crys-tallographic surface orientations is reported. The quality of the crystal structure of epitaxial samples is assessed using the atomic force microscopy of their surface. The manifestation of a piezoelectric field in the photoluminescence spectra is reported.