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The reaction between Gd2O3 (I) and NH4I (II) which is investigated thermogravimetrically between 20 and 500 °C affords the title compound, i.e. GdOI (III).
Die Titelverbindung bildet mit wasserfreiem GaCl3 in Benzol in Abhängigkeit von der eingesetzten GaCl3‐Menge kristalline Komplexe mit einem Metall : Ligand‐Verhältnis wie 1:1 oder 2:1 (Elektronenabsorptionsspektren, IR‐Absorption; Ausbeuteangaben ifehlen).
Nach literaturbekanntem Verfahren werden die bisher nicht beschriebenen Verbindungen Rb2Nd(NO3)5 ‐H2O und Cs2Nd(NO3)5 ‐H2O erhalten und durch IR‐ und Röntgenanalyse und thermische Zersetzung charakterisiert.
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