The effects of cellulose nanocrystals
(CNCs) (12, 24, and 36% w/w)
on the microstructure and mechanical and thermal properties of canola
protein isolate films were evaluated. The incorporation of cellulose
nanocrystals led to homogeneous films, and new Fourier transform infrared
peaks appeared at 1055 cm–1, indicating the presence
and the interaction of CNCs with proteins and glycerol. The addition
of CNCs also improved the thermal stability of the films, since higher
temperatures were required for their thermal decomposition. In addition,
CNC addition resulted in an increase in tensile strength and a decrease
in elongation at break values due to strong interactions between the
OH groups in proteins, glycerol, and CNCs.
Protein concentrates from jatropha (JPC) and soy seeds (SPC) were obtained by solubilization and acid precipitation of proteins. JPC and SPC films were prepared by the casting method, using two different montmorillonite (MMT) clay concentrations and plasticized with glycerol. Film properties were evaluated by scanning electron microscopy, transmission electron microscopy, Xray diffraction (XRD), Fourier transform infrared spectroscopy, thermogravimetric analysis, tensile properties, water retention, and water vapor transmission rate (WVRT). Typical tactoid microcomposite structures were found to be heterogeneously dispersed in the films containing MMT. A small XRD peak was found in films with MMT. Slight improvements in thermal stability and tensile strength were observed in the films with MMT. Reductions in water retention and WVRT were obtained when MMT was added into the films.
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