Resistive switching (RS) is an interesting property shown by some materials systems that, especially during the last decade, has gained a lot of interest for the fabrication of electronic devices, with electronic nonvolatile memories being those that have received the most attention. The presence and quality of the RS phenomenon in a materials system can be studied using different prototype cells, performing different experiments, displaying different figures of merit, and developing different computational analyses. Therefore, the real usefulness and impact of the findings presented in each study for the RS technology will be also different. This manuscript describes the most recommendable methodologies for the fabrication, characterization, and simulation of RS devices, as well as the proper methods to display the data obtained. The idea is to help the scientific community to evaluate the real usefulness and impact of an RS study for the development of RS technology.
International audienceWe report a study of resistive switching in a silicon-based memristor/resistive RAM (RRAM)device in which the active layer is silicon-rich silica. The resistive switching phenomenon is anintrinsic property of the silicon-rich oxide layer and does not depend on the diffusion of metallicions to form conductive paths. In contrast to other work in the literature, switching occurs inambient conditions, and is not limited to the surface of the active material. We propose a switchingmechanism driven by competing field-driven formation and current-driven destruction offilamentary conductive pathways. We demonstrate that conduction is dominated by trap assistedtunneling through noncontinuous conduction paths consisting of silicon nanoinclusions in a highlynonstoichiometric suboxide phase. We hypothesize that such nanoinclusions nucleate preferentiallyat internal grain boundaries in nanostructured films. Switching exhibits the pinched hysteresis I/Vloop characteristic of memristive systems, and on/off resistance ratios of 104:1 or higher can beeasily achieved. Scanning tunneling microscopy suggests that switchable conductive pathways are10 nm in diameter or smaller. Programming currents can be as low as 2 lA, and transition timesare on the nanosecond scale
The overlap of the principal luminescence band of the erbium ion with the low-loss optical transmission window of silica optical fibres, along with the drive for integration of photonics and silicon technology, has generated intense interest in doping silicon with erbium to produce a silicon-based optical source. Silicon is a poor photonic material due to its very short non-radiative lifetime and indirect band gap, but it has been hoped that the incorporation of optically active erbium ions into silicon will permit the development of silicon-based light sources that will interface with both CMOS technology and optical fibre communications. Some years into this activity, there have now been a wide range of experimental studies of material growth techniques, optical, physical and electrical properties, along with a considerable body of theoretical work dealing with the site of the erbium ion in silicon, along with activation and deactivation processes. This paper reviews the current state of what remains an active field, summarizing results from a range of studies conducted over the last few years, and points to further developments by considering the prospects for successful photonic integration of erbium and silicon.
Resistive switching offers a promising route to universal electronic memory, potentially replacing current technologies that are approaching their fundamental limits. In many cases switching originates from the reversible formation and dissolution of nanometre-scale conductive filaments, which constrain the motion of electrons, leading to the quantisation of device conductance into multiples of the fundamental unit of conductance, G0. Such quantum effects appear when the constriction diameter approaches the Fermi wavelength of the electron in the medium – typically several nanometres. Here we find that the conductance of silicon-rich silica (SiOx) resistive switches is quantised in half-integer multiples of G0. In contrast to other resistive switching systems this quantisation is intrinsic to SiOx, and is not due to drift of metallic ions. Half-integer quantisation is explained in terms of the filament structure and formation mechanism, which allows us to distinguish between systems that exhibit integer and half-integer quantisation.
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