In this article, we present a critical review of the reported performance of reverse osmosis (RO) and capacitive deionization (CDI) for brackish water (salinity < 5.0 g/L) desalination from the aspects of engineering, energy, economy and environment. We first illustrate the criteria and the key performance indicators to evaluate the performance of brackish water desalination. We then systematically summarize technological information of RO and CDI, focusing on the effect of key parameters on desalination performance, as well as energy-water efficiency, economic costs and environmental impacts (including carbon footprint). We provide in-depth discussion on the interconnectivity between desalination and energy, and the trade-off between kinetics and energetics for RO and CDI as critical factors for comparison. We also critique the results of technical-economic assessment for RO and CDI plants in the context of large-scale deployment, with focus on *Manuscript Click here to view linked References 2 lifetime-oriented consideration to total costs, balance between energy efficiency and clean water production, and pretreatment/post-treatment requirements. Finally, we illustrate the challenges and opportunities for future brackish water desalination, including hybridization for energy-efficient brackish water desalination, co-removal of specific components in brackish water, and sustainable brine management with innovative utilization. Our study reveals that both RO and CDI should play important roles in water reclamation and resource recovery from brackish water, especially for inland cities or rural regions.
Wear of fixed abrasive diamond wire affects the quality of sliced silicon wafers, necessitating replacement of the costly wire. This paper analyzes the effect of wire wear on the surface morphology, roughness, and subsurface damage of as-cut single crystal silicon wafers. Scanning electron microscopy, confocal microscopy, and focused ion beam machining (FIB) are used to evaluate the surface morphology, areal surface roughness, and subsurface damage (cracks). Results show that, with increased wire wear, the wafers exhibit greater evidence of ductile removal, lower surface roughness, fewer but slightly deeper subsurface cracks, and lower average fracture strength.
Millions of people are exposed to
toxic levels of dissolved arsenic
in groundwater used for drinking. Iron electrocoagulation (FeEC) has
been demonstrated as an effective technology to remove arsenic at
an affordable price. However, FeEC requires long operating times (∼hours)
to remove dissolved arsenic due to inherent kinetics limitations.
Air cathode Assisted Iron Electrocoagulation (ACAIE) overcomes this
limitation by cathodically generating H2O2 in
situ. In ACAIE operation, rapid oxidation of Fe(II) and complete oxidation
and removal of As(III) are achieved. We compare FeEC and ACAIE for
removing As(III) from an initial concentration of 1464 μg/L,
aiming for a final concentration of less than 4 μg/L. We demonstrate
that at short electrolysis times (0.5 min), i.e., high charge dosage
rates (1200 C/L/min), ACAIE consistently outperformed FeEC in bringing
arsenic levels to less than WHO-MCL of 10 μg/L. Using XRD and
XAS data, we conclusively show that poor arsenic removal in FeEC arises
from incomplete As(III) oxidation, ineffective Fe(II) oxidation and
the formation of Fe(II–III) (hydr)oxides at short electrolysis
times (<20 min). Finally, we report successful ACAIE performance
(retention time 19 s) in removing dissolved arsenic from contaminated
groundwater in rural California.
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