Within this study, phytochemical, fatty acid and proximal composition of six Indonesian brown rice cultivars (Inpari 42, Inpari 43, Situ Bagendit, IPB3 S, Inpari 17, and Inpara 3) were reported. The range of moisture, ash, crude fat, crude protein, and total carbohydrates content of six varieties of brown rice were 11-12%, 1.3-1.4%, 2-3%, 7-11%, and 84-89%, respectively. Fatty acid composition of brown rices was dominated by unsaturated fatty acids. The phenolic contents and IC 50 of all cultivars varied from 47 to 70 mg GAE/100 g and 28-47 mg/mL, respectively. Inpari 17 had the highest phenolic content as well as antioxidant activity, whereas IPB 3 S variety exhibited the lowest in both γ-oryzanol content of brown rices ranged from 37 to 55 mg/100 g. The highest content of γoryzanol was observed in Inpara 3. In conclusion, six varieties of Indonesian brow rice might be considered as the potent sources of bioactive compounds and antioxidant, especially in Inpari 17 variety.Composición fitoquímica, de ácidos grasos y proximal de seis variedades seleccionadas de arroz integral indonesio RESUMEN El presente estudio se propuso informar sobre la composición fitoquímica, de ácidos grasos y proximal de seis cultivares de arroz integral indonesio (Inpari 42, Inpari 43, Situ Bagendit, IPB3S, Inpari 17 e Inpara 3). Se constató que el grado de contenido de humedad, cenizas, grasa bruta, proteína bruta y total de carbohidratos de seis variedades de arroz integral fue de 11-12%, 1.3-1.4%, 2-3%, 7-11% y 84-89%, respectivamente. En la composición de ácidos grasos de los arroces integrales predominan los ácidos grasos insaturados. El contenido fenólico y el IC 50 de todos los cultivares variaron entre 47-70 mg GAE/100g y 28-47 mg/mL, respectivamente. El Inpari 17 presentó el mayor contenido fenólico y la mayor actividad antioxidante, mientras que la variedad IPB 3S exhibió el contenido más bajo de ambos factores. El contenido de γ-orizanol de los arroces integrales varió entre 37-55 mg/100g. El mayor contenido de γ-orizanol se observó en el Inpara 3. Tales resultados permiten concluir que estas seis variedades de arroz integral indonesio podrían considerarse fuentes potentes de compuestos bioactivos y antioxidantes, destacándose en este sentido la variedad Inpari 17.

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SUMMARYMedium-long-medium (MLM) structured lipids typically contain medium-chain fatty acids (C6-C12) at sn-1,3 and long-chain fatty acids (C14-C24) at sn-2 positions. They have reduced calories and are suitable for the control of obesity, lipid malabsorption and other metabolic disorders. This review focuses on the synthesis of MLM lipids by the enzymatic interesterification. It gives detailed description of biocatalysts, substrates, reactors and synthesis methods, and discusses the use of MLM lipids in food products. The information provided in this review can be considered as the current state-of-the art for developing a future strategy for the synthesis of MLM structured lipids.

Lactulose, a synthetic disaccharide, has received increasing interest due to its role as a prebiotic. The production of lactulose is important in the dairy industry, as it is regarded as a high value-added derivative of whey or lactose. The industrial production of lactulose is still mainly done by chemical isomerization. Due to concerns on the environmental and tedious separation processes, the enzymatic-based lactulose synthesis has been regarded as an interesting alternative. This work aims at comparing chemical and enzyme-catalyzed lactulose synthesis. With an emphasis on the latter one, this review discusses the influences of the critical operating conditions and the suited operation mode on the transgalactosylation of lactulose using microbial enzymes. As an update and supplement to other previous reviews, this work also summarizes the recent reports that highlighted the enzymatic isomerization of lactose using cellobiose 2-epimerase to produce lactulose at elevated yields.