The evolution of surface morphology, crystallinity, and growth modes of c-axis-oriented superconducting YBa2Cu3O7−x (YBCO) thin films deposited by pulsed laser deposition on SrTiO3(100) and NdGaO3(110) substrates have been systematically investigated with scanning electron microscopy (SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM), x-ray energy-dispersive spectroscopy, and x-ray diffraction. SEM and AFM images of the YBCO films grown on NdGaO3 with a sequential thickness revealed that the films were rather smooth and grew in a two-dimensional manner. In contrast, the YBCO films of the same thickness on SrTiO3 were found to have spiral growth features, even in the thinnest film (10 nm or 8 unit cells thick) indicating that an island growth mechanism took place. A change of the full width at half-maximum of the rocking curves of the (005) reflection with the film thickness showed that the crystallinity of the films on NdGaO3 was much better than those grown on SrTiO3, suggesting that a lattice match is a crucial factor to obtain good crystallinity. In the early stages of growth the preferential a-axis orientation of the films on NdGaO3, as revealed by TEM, was consistent with the smooth and featureless film surfaces found, in contrast to the c-axis growth mode on SrTiO3.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.