Silver nanowires have been synthesized by a polyol process. A detailed parametric study determining the relationship between final morphology of the products and temperature, injection rate, molar ratio of poly(vinylpyrrolidone) to silver nitrate, sodium chloride amount, and stirring rate is presented. The as-synthesized silver nanowires are analyzed by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The dependency of nanowire morphology and aspect ratio on synthesis parameters is shown via SEM images. Furthermore, the nanowire diameter is found to decrease with stirring rate, poly(vinylpyrrolidone) to silver nitrate molar ratio, and temperature and to increase with injection rate. The lack of sodium chloride and its presence in excess amounts resulted in the formation of particles with different sizes in addition to nanowires. In addition, poly(vinylpyrrolidone) to silver nitrate molar ratio is found to affect the morphology of the resulting nanostructure, leading to formation of particles at high and low ends. The results reported in this paper provide a basis for optimizing silver nanowire growth through the self-seeding polyol method.
We report on the fabrication and characterization of all nanowire (NW) network photodetectors. For this purpose, germanium (Ge) NW networks are used as active semiconducting elements, whereas single walled carbon nanotube (SWNT) and silver (Ag) NW networks are used as the contacts. Following their synthesis, all NW networks are deposited through simple solution based methods. Photoresponse characteristics and transparency of the photodetectors for different Ge NW densities are measured. The fabricated devices show a large response with short relaxation times (<10 ms), are flexible and transparent within the visible spectrum.
In this study, the efficiency of halogen···halogen interactions to control over the supramolecular assemblies of boron dipyrromethene (BODIPY) (B1-B5) derivatives was explored. BODIPY scaffolds were systematically decorated with iodine group...
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