The influence of B2O3 on the viscosity of high Ti-bearing BF slag is studied under Ar atmosphere from 1 773 K (1 500°C) to about 1 593 K (1 320°C). The results show that the addition of B2O3 can decrease the viscosity of high Ti-bearing BF Slag containing UPC, consequently improve its fluidity. With the existence of 1.5% UPC, when the content of B2O3 increased from 0 to 4.1%, the volume fraction of perovskite decreased from 7.7% to 1.6% at 1 610 K. Meanwhile, the liquidus temperatures decreased from 1 619 K to 1 613 K. At a lower temperature, B2O3 was easy to form a eutectic and decreased the viscosity of molten slag. At a higher temperature, some tetrahedron [BO4] 5-changed into triangle [BO3] 3-which would disintegrate the chains/molecules of molten matrix and decreased its viscosity.KEY WORDS: Ti-bearing blast furnace slag; viscosity; B2O3.
Iron ore's assimilation characteristic reflecting the beginning formation temperature of liquid phase in sintering process plays very important role on the fluidity of liquid phase and bonding strength of sinter body. Experimental study of assimilation characteristics of 12 kinds of iron ores were conducted using micro-sinter equipment, and pure reagent simulating tests of assimilation characteristic were also carried out for the purpose of achieving the influence of chemical composition on the assimilation characteristic. In addition, effects of assimilation characteristic of iron ore on the fluidity and bonding capacity of bonding phase were also researched. This study showed that SiO2 and LOI promoted the assimilation of iron ore, low Al2O3 (<1.5 mass%) was good to the assimilation, but high Al2O3 (≥1.5 mass%) was bad, MgO was adverse to assimilation of magnetite concentrate. In addition, lower assimilation temperature of iron ore led to higher superheat degree of liquid phase at a certain sintering temperature, then higher liquid fluidity and bonding strength.
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