Nickel–iron
based materials are well-known
catalysts for the oxygen evolution
reaction (OER) and have been widely investigated. However, the synergy
between these two components is still controversial. Herein, we report
a facile immersion method for the synthesis of binder-free nickel–iron
hydroxide loaded on Ni foam (NiFe-OH/NF) with superior hydrophilic
property and high OER catalytic activity. The strong hydrophilic property
of the binder-free NiFe-OH/NF electrode significantly enhances an
effective contact between electrocatalyst and aqueous electrolyte
and favors the bubble detachment from the electrode, facilitating
the electron transfer and improving the OER activity. The hydrophilic
NiFe-OH/NF can achieve a geometrical current density of 100 mA cm–1 at an extremely low overpotential (219 mV), along
with a Tafel slope of 56 mV dec–1 and superior long-term
stability at high current density in alkaline media, strongly indicating
that the hydrophilicity plays an important role in improving the OER
performance in the NiFe-OH/NF.
Polycrystalline alloy electrodes of Pt with alkaline earth metals (Ca, Sr, and Ba) have been shown to exhibit enhanced electrocatalytic performance for oxygen reduction reaction (ORR) relative to Pt electrodes. The large oxophilicity of the alkaline earth metals makes it challenging to synthesize such alloys. Here, we synthesize a carbon-supported platinum−magnesium (PtMg) alloy with enhanced catalytic activity and durability for the ORR in both a half-cell and single cell when compared to the state-of-the-art Pt/C catalyst. Employing metallic Mg powder as a precursor can overcome the large oxophilicity of Mg and induce alloying of Mg with Pt, whereas conventional Mg salts do not form an alloy. Density functional theory calculations elucidate the origin of the enhanced catalytic activity and durability. Complementary physical and electrochemical analyses also evidence them in this work. This material holds great application potential and will contribute to elucidation of the effects of alloying Pt with electropositive metals.
In this study, monodisperse polystyrene nanospheres were prepared by dispersion polymerization using alcohol as reaction medium to prepare colloidal clusters of the latex beads. Polyvinylpyrrolidone (PVP) and 2-(methacryloyloxy)ethyltrimethylammonium chloride (MTC) were used as dispersion stabilizer and comonomer, respectively. The particle size could be controlled by adjusting the reactant compositions such as the amount of stabilizer, comonomer, and water in the reactant mixture. The size and monodispersity of the polymeric particles could be also controlled by changing the reaction medium with different alcohols other than ethanol or adjusting the polymerization temperature. The synthesized particles could be self-organized inside water-in-oil emulsion droplets by evaporation-driven self-assembly to produce colloidal clusters of the polymeric nanospheres.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.