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Detonation structures generated by wedge-induced, oblique shocks in hydrogen-oxygennitrogen mixtures were investigated by time-dependent numerical simulations. The simulations show a multidimensional detonation structure consisting of the following elements: (1) a nonreactive, oblique shock, (2) an induction zone, (3) a set of deflagration waves, and (4) a "reactive shock," in which the shock front is closely coupled with the energy release. In a wide range of flow and mixture conditions, this structure is stable and very resilient to disturbances in the flow. The entire detonation structure is steady on the wedge when the flow behind the structure is completely supersonic. If a part of the flow behind the structure is subsonic, the entire structure may become detached from the wedge and move upstream continuously.

A low-temperature ozone exposure technique was employed for the post-treatment of WO(x) nanorod thin films fabricated from hot-wire chemical vapor deposition (HWCVD) and ultrasonic spray deposition (USD) techniques. The resulting films were characterized with x-ray diffraction (XRD), transmission electron microscopy (TEM), Raman spectroscopy, UV-vis-NIR spectroscopy and x-ray photoelectron spectroscopy (XPS). The stoichiometry and surface crystallinity of the WO(x) thin films were subsequently modulated upon ozone exposure and thermal annealing without particle growth. The electrochromic performance was studied in a LiClO(4)-propylene carbonate electrolyte, and the results suggest that the low-temperature ozone exposure technique is superior to the traditional high-temperature thermal annealing (employed to more fully oxidize the WO(x)). The optical modulation at 670 nm was improved from 35% for the as-deposited film to 57% for the film after ozone exposure at 150 °C. The coloration efficiency was improved and the switching speed to the darkened state was significantly accelerated from 18.0 s for the as-deposited film to 11.8 s for the film after the ozone exposure. The process opens an avenue for low-temperature and cost-effective manufacturing of electrochromic films, especially on flexible polymer substrates.

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