To explore the purification effect of biochar-constructed wetlands on rural domestic sewage, six types of biochar-constructed wetlands were constructed for experiments. Under different hydraulic conditions, the removal effects of each biochar-constructed wetland on chemical oxygen demand, ammonia nitrogen, total nitrogen, and total phosphorus in sewage were analyzed. The results showed that the removal rates of the four types of pollutants in each biochar-constructed wetland first increased and then decreased with the increase in hydraulic retention time, and the optimal hydraulic retention time range was 36–48 h. The highest removal rates of chemical oxygen demand, ammonia nitrogen, total nitrogen, and total phosphorus in the wetland were 97.34 ± 0.84%, 95.44 ± 1.29%, 98.95 ± 0.52%, and 97.78 ± 0.91%, respectively. The chemical oxygen demand (COD) removal rate of each biochar-constructed wetland increased first, then decreased with the increase in hydraulic load, and the optimal hydraulic load was 10 cm/d. The removal efficiency of ammonia nitrogen, total nitrogen, and total phosphorus of each biochar-constructed wetland gradually weakened with the increase in hydraulic load, and the optimal hydraulic load range was between 5 and 10 cm/d. Under these conditions, the highest removal rates of chemical oxygen demand, ammonia nitrogen, total nitrogen, and total phosphorus in the wetland were 92.15 ± 2.39%, 98.32 ± 0.48%, 96.69 ± 1.26%, and 92.62 ± 2.92%, respectively. Coconut shell and shell-constructed wetlands with the highest proportion of biochar in the matrix have the best removal effect on pollutants under different hydraulic conditions, and the wastewater purification effect is stronger, indicating that the addition of biochar is helpful for the removal of pollutants in constructed wetlands.

Throughout the last few decades, sulfate concentrations in streamwater have received considerable attention due to their dominant role in anthropogenic acidification of surface waters. In order to determine the cycle of riverine sulfate, affected by natural weathering and anthropogenic activities, the Zhuzhaoxin River Basin and Dongyu River Basin in Heze City, China are selected. The conventional hydrochemical characteristics, distribution characteristics of sulfate concentration, and distribution characteristics of sulfur and oxygen isotopes are analyzed and texted. The results are as follows: The concentration of SO42− in the surface water of the study area increased gradually from upstream to downstream. In the study area, the δ34SSO4 and δ18OSO4 value in the surface water of Zhuzhaoxin River Basin ranges from +8.0‰ to +22.3‰ and +7.3‰ to +10.5‰, respectively, while the values of Dongyu River Basin are between +9.3‰ ∼ +9.5‰ and +4.2‰ ∼ +8.1‰. The main sources of SO42− in the Zhuzhaoxin River Basin are domestic sewage, industrial and mining wastewater and the evaporation of dissolved salt rock, and their average contribution rates are more than 50 and 30% respectively; the main sources of SO42− in the Dongyu River Basin are agricultural activities and atmospheric precipitation, and their average contribution rates are more than 60 and 20%, respectively.