Double side light emission devices based on p-NiO/n-ZnO nanowire heterojunctions have been fabricated on indium tin oxide substrate by radio frequency magnetron sputtering combined with hydrothermal process. According to the energy band alignment, the detected broad visible and narrow ultraviolet electroluminescence arise from defect and band edge transitions in ZnO nanowires, respectively. The unique property of the double side emission is due to the nature of the large band gap of NiO film. It provides a good opportunity for the emission of a light emitting device with different colors on the top and back sides, simultaneously.
The authors report ultraviolet electroluminescence from ZnO nanoparticle-based devices prepared by the phase-segregation technique. The conditions for phase segregation are investigated using confocal microscopy. With proper parameters for phase segregation, the ZnO nanoparticles and N , NЈ-diphenyl-N , NЈ-bis͑3-methylphenyl͒-1,1Ј-biphenyl-4 , 4Ј-diamine: poly͑methyl methacrylate͒ can be separated into two layers upon spin-coating process. The method allows electrons and holes to recombine in the ZnO nanoparticles. The I-V curve shows stable and excellent rectification. For the device with 90 nm ZnO nanoparticles, it exhibits a very narrow spectrum with a peak at 392 nm and no defect-related emission. The emission peak well corresponds to the ZnO band-gap energy.
We report ultraviolet electroluminescence from ZnO nanoparticle-based devices prepared by the dry-coating technique. With dry-coating process, the structure of the ZnO nanoparticle monolayer ͑90 nm͒ in the device can be easily achieved. The method reduces the density of pinhole defects in the ZnO nanoparticles. The confirmation for dry coating is investigated using field-emission scanning electron microscopy. The devices show the ZnO band-gap emission peak at 380 nm and the background emission from the interface between the host matrix and Aluminum tris-8-hydroxyquinoline. The origins of the ZnO band-gap emission and background emission are also discussed.
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