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Radiation is the principal mode of heat transfer in furnaces. Models for gaseous radiative properties have been well-established for air combustion. However, there is uncertainty regarding their applicability to oxy−fuel conditions. In this paper, a new and complete set of weighted sum of gray gases model (WSGGM) is derived, which is applicable to computational fluid dynamics (CFD) modeling of both air−fuel and oxy−fuel combustion. First, a computer code is developed to evaluate the emissivity of any gas mixture at any condition using the exponential wide band model (EWBM), and the calculated results are validated in detail against data in the literature. Then, the validated code is used to generate emissivity databases for representative air- and oxy-firing conditions, for each of which a refined WSGGM with new parameters is derived. The practical way to implement the model to CFD simulations of combustion systems is given. Finally, as a demonstration, the new model is implemented to CFD modeling of two furnaces of very different beam lengths. The CFD results are compared to those based on the widely used WSGGM in the literature, from which some useful guidelines on oxy−fuel modeling are recommended.

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