The photopolymerization kinetics of typical dental dimethacrylate monomers were studied
by differential photocalorimetry. Increasing proportions of the low-viscosity diluent monomer triethylene
glycol dimethacrylate (TEGDMA) were added to either Bis-GMA (2,2-bis[p-(2‘-hydroxy-3‘-methacryloxypropoxy)phenylene]propane), EBADMA (ethoxylated bisphenol A dimethacrylate), or UDMA (1,6-bis(methacryloxy-2-ethoxycarbonylamino)-2,4,4-trimethylhexane) to provide three base resins that differed
in their hydrogen-bonding potential and, therefore, resulted in compositions covering a broad range of
viscosities. When compared at similar diluent concentrations, UDMA resins were significantly more
reactive than Bis-GMA and EBADMA resins. At higher diluent concentrations, EBADMA resins provided
the lowest photopolymerization reactivities. Optimum reactivities in the UDMA and EBADMA resin
systems were obtained with the addition of relatively small amounts of TEGDMA, whereas the Bis-GMA/TEGDMA resin system required near equivalent mole ratios for highest reactivity. The hydrogen-bonding interactions, which substantially influence the Bis-GMA and UDMA resin series, were examined
by Fourier transform infrared spectroscopy and resin viscosity. Synergistic effects of base and diluent
monomer on the polymerization rate and the final conversion were found for the two base resins having
hydrogen-bonding interactions. The structures of the individual monomers and, consequently, the resin
viscosities of the comonomer mixtures strongly influence both the rate and the extent of conversion of
the photopolymerization process.
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