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Low temperature selective silicon epitaxy was studied over a range of process pressures and HCI flows using a SiH2Cl2/HCl/H2 based chemistry. Thermodynamic modelling was carried out with the aid of the SOLGAS program to investigate the effect of process pressure, HCI flow rate, and leaks on the distribution of gas phase species. Selectivity results are interpreted in terms of the defect microchemistry on SiO2 surfaces.

Metalorganic chemical vapor deposition (MOCVD) titanium silicon nitride (TiSiN) has emerged as a strong candidate for a next-generation diffusion barrier material in copper/low-k dielectric back-end-of-line (BEOL) device fabrication. As ionized physical vapor deposition (PVD) Ta(N) barriers currently used in high-volume production begin to exhibit marginal film continuity in high aspect ratio device features, more conformal barrier materials become a requirement. Material, electrical, and reliability properties are strongly influenced by CVD TiSiN film thickness, process sequencing, and incoming surface cleanliness of device features. TiSiN has been shown to possess the necessary material and electrical properties to be successfully integrated in sub-130 nm copper/low-k semiconductor device technology nodes.

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The advent of inlaid Cu interconnects has presented new challenges for the industry to fill high aspect ratio dual inlaid features. CVD Cu offers advantages for excellent step coverage and is a technique extendible for future generations of devices. We have developed a robust CVD Cu process and a CVD/PVD reflow integration scheme. In this paper, we present results of an extensive study on CVD Cu process development and integration. The effects of various precursors, carrier gases (H2, He and N2) and barrier layers including CVD TiN, PVD Ta, PVD TaN, PVD Ta-Si-N, and a hybrid barrier, on the CVD Cu film properties and device electrical properties are discussed. The extendibility and challenges of current CVD Cu processing will also be discussed.