The thermally stimulated and tunneling luminescence spectra of X‐irradiated KCl and KBr, as well as thermal bleaching and thermally stimulated current of X‐irradiated KBr are studied at 4.2 to 77 K. The activation energies of I‐ and H‐centre thermal diffusion are determined. The possibilities of radiative tunneling charge transfer and radiative recombination of the F‐ and H‐centres, as well as possible mechanisms of I‐centre production are considered.
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