Economics of creating CO 2 hydrate on a large scale favor use of gaseous rather than liquid CO 2 as input to the production process. We accordingly studied systems using deionized water and CO 2 gas to reduce formation pressures and costs of hydrate production to the greatest extent possible. Three research avenues were explored: utilization of hysteresis effects, use of dissolved Snomax (a protein from the bacterium Pseudomonas syringae), and development of a continuous flow reactor (cfr) utilizing vigorous mixing of water and CO 2 gas. Hysteresis effects produced pressure reductions of 14-50%. We demonstrated a method of transferring benefits from the hysteresis effect to a CO 2 water mixture that had not yet undergone hydrate formation. Snomax at 10 ppm by weight produced about a 5% reduction in hydrate formation pressure. We designed and operated a prototype cfr with partial success at producing CO 2 hydrate. The hydrate phase diagram is based on hydrate decomposition pressures and should not be used as an indicator of formation pressures.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.