The aerobic oxidative CÀC bond cleavage of vicinal diols catalyzed by vanadium amino triphenolates is described. Our results show that CÀC bond cleavage can be performed in different solvents, under an air or oxygen atmosphere, with a large variety of glycols (cyclic or linear, with aromatic or aliphatic substituents) affording the corresponding carbonyl derivatives with high chemoselectivity.Reactions can be performed with as little as 10 ppm of catalyst reaching TON up to 81,000 and TOFs of up to 4150 h À1 . A reaction mechanism, rationalized by density functional theory calculations, is also proposed.

Intermolecular interactions sensitive to chirality occur in many biological events. We report a complex formation between a versatile vanadium-based probe and a chiral co-ligand monitored through the interference of electronic...

Recent developments in fluvial geomorphology and sedimentology suggest that fluvial fans (also known as distributive fluvial systems) could be responsible for the accumulation of great volumes of clastic successions in continental basins. A general depositional model based on sedimentological and architectural trends has been formulated for these fluvial systems, however, their recognition in the stratigraphic record often relies on partially preserved, discontinuous successions. This study provides a sedimentological and architectural characterization of Paleogene alluvial strata of the Wasatch and Colton formations in the southwestern Uinta Basin, central Utah (U.S.A.), following an ∼ 120-km-long outcrop belt which records deposition from an alluvial wedge that prograded to the north and northwest, from the basin margin to distal lake-dominated environments, preceding the onset of ancient Lake Uinta. Lateral and vertical distribution of facies associations are presented from a dataset of field observations (thirteen logged stratigraphic sections, for a total of ∼ 2400 m) and virtual outcrop models along the proximal-to-distal extent of the Wasatch–Colton alluvial system. Four sectors are defined (proximal, medial, distal, and terminal) to mark the longitudinal heterogeneity of alluvial stratigraphy. Noteworthy trends comprise a downstream decrease in the overall thickness of the alluvial stratigraphic column, a reduction in the relative volume, architectural complexity, and amalgamation of fluvial-channel bodies away from the apex, a weak downstream-fining trend in channel sandstones, and a down-system increase in preserved overbank and floodplain deposits accompanied by increasing volume and facies complexity of preserved lacustrine and palustrine facies associations. A proximal-to-distal change in fluvial-channel architecture is noted, with proximal sections characterized by vertically and laterally amalgamated sheet-like channel fills, transitioning to a lesser degree of amalgamation towards the medial sector, whereas distal and terminal sections are dominated by floodplain fines enveloping a subordinate volume of isolated, ribbon-shaped channel-sandstone bodies. The temporal development of the stratigraphic succession is observed in its entirety throughout the field area and, albeit localized, channel-scale erosion and potential depositional hiatuses punctuate the stratigraphy. Two major system-scale trends have been described in the Wasatch–Colton System (WCS). A first-order, long-term progradational trend, especially evident in proximal and medial sections, encompasses the large-scale vertical patterns in facies and architecture vertically through most of the stratigraphy of the WCS. In contrast, the uppermost part of the stratigraphic succession is characterized by a reverse, retrogradational trend, possibly associated with the early transgression of Lake Uinta's southern margin, marking the base of the overlying Green River Formation. Albeit expressed by different vertical succession of facies, proximal-to-distal processes, and stratal patterns documented along a longitudinal transect of the WCS mirror substantially identical vertical trends through the stratigraphy, which are interpreted as Waltherian superposition of distinct depositional domains during fluvial-fan progradation. Analyses of sandstone petrography and zircon geochronology suggest a unified source for the fluvial system, also supporting an interpretation as a distributive, rather than a tributive, fluvial system. This study enhances our understanding of the current depositional model for extensive fluvial-fan successions via a regional-scale stratigraphic analysis of a fluvial paleo-fan based on integrated characterization of both vertical and down-system patterns in facies distribution and fluvial architecture, providing key insights on useful criteria for recognizing fluvial-fan successions from the rock record.

The inside cover picture, provided by Giulia Licini, Carles Bo and coworkers illustrates the highly chemoselective aerobic oxidative cleavage of 1,2‐diols to the corresponding carbonyl derivatives catalyzed by vanadium‐aminotriphenolate complexes. This catalytic method works with a large variety of glycols, linear or cyclic, with aromatic or aliphatic substituents. Pre‐association of the substrate to the metal center, followed by a two‐electron oxidation mechanism, yields the carbonyl derivatives and a reduced VIII metal complex, which is rapidly oxidized back to the catalyst by O2. Details of this work can be found in the full paper on pages 3281–3291 (E. Amadio, J. González‐Fabra, D. Carraro, W. Denis, B. Gjoka, C. Zonta, K. Bartik, F. Cavani, S. Solmi, C. Bo, G. Licini, Adv. Synth. Catal. 2018, 360, 3281–3291; DOI: 10.1002/adsc.201800050).