Capturing carbon dioxide (CO(2)) emissions from industrial sources and injecting the emissions deep underground in geologic formations is one method being considered to control CO(2) concentrations in the atmosphere. Sequestering CO(2) underground has its own set of environmental risks, including the potential migration of CO(2) out of the storage reservoir and resulting acidification and release of trace constituents in shallow groundwater. A field study involving the controlled release of groundwater containing dissolved CO(2) was initiated to investigate potential groundwater impacts. Dissolution of CO(2) in the groundwater resulted in a sustained and easily detected decrease of ~3 pH units. Several trace constituents, including As and Pb, remained below their respective detections limits and/or at background levels. Other constituents (Ba, Ca, Cr, Sr, Mg, Mn, and Fe) displayed a pulse response, consisting of an initial increase in concentration followed by either a return to background levels or slightly greater than background. This suggests a fast-release mechanism (desorption, exchange, and/or fast dissolution of small finite amounts of metals) concomitant in some cases with a slower release potentially involving different solid phases or mechanisms. Inorganic constituents regulated by the U.S. Environmental Protection Agency remained below their respective maximum contaminant levels throughout the experiment.

[1] The Ama Drime Massif (ADM) is an elongate north-south trending antiformal feature that extends $70 km north across the crest of the South Tibetan Himalaya and offsets the position of the South Tibetan Detachment system. A detailed U(-Th)-Pb geochronologic study of granulitized mafic eclogites and associated rocks from the footwall of the ADM yields important insights into the middle to late Miocene tectonic evolution of the Himalayan orogen. The mafic igneous precursor to the granulitized eclogites is 986.6 ± 1.8 Ma and was intruded into the paleoproterozoic (1799 ± 9 Ma) Ama Drime orthogneiss, the latter being similar in age to rocks previously assigned to the Lesser Himalayan Series in the Himalayan foreland. The original eclogite-facies mineral assemblage in the mafic rocks has been strongly overprinted by granulite facies metamorphism at 750°C and 0.7-0.8 GPa. In the host Ama Drime orthogneiss, the granulite event is correlated with synkinematic sillimanite-grade metamorphism and muscovite dehydration melting. Monazite and xenotime ages indicate that the granulite metamorphism and associated anatexis occurred at <13.2 ± 1.4 Ma. High-grade metamorphism was followed by postkinematic leucogranite dyke emplacement at 11.6 ± 0.4 Ma. This integrated data set indicates that high-temperature metamorphism, decompression, and exhumation of the ADM postdates mid-Miocene south directed midcrustal extrusion and is kinematically linked to orogen-parallel extension. Citation: Cottle,

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Geochemical study of water and gas discharging from the deeply incised aquifer system at the Grand Canyon, Arizona, provides a paradigm for understanding complex groundwater mixing phenomena, and Quaternary travertines deposited from cool springs provide a paleohydrologic record of this mixing. Geochemical data show that springs have marked compositional variability: those associated with active travertine accumulations (deeply derived endogenic waters) are more saline, richer in CO 2 , and elevated in 87 Sr/ 86 Sr relative to springs derived dominantly from surface recharge of plateau aquifers (epigenic waters). Endogenic waters and associated travertine are preferentially located along basement-penetrating faults. We propose a model whereby deeply derived fluids are conveyed upward via both magmatism and seismicity. Our model is supported by: (1) gas analyses from spring waters with high He/Ar and He/N 2 and 3 He/ 4 He ratios indicating the presence of mantle-derived He; (2) large volumes of travertine and CO 2-rich gases in springs recording high CO 2 fluxes; and (3) 87 Sr/ 86 Sr in these springs that indicate circulation of waters through Precambrian basement. Geochemical trends are explained by mixing of epigenic waters of the Colorado Plateau aquifers with different endogenic end-member waters in different tectonic subprovinces. Endogenic waters are volumetrically minor but have significant effects on water chemistry. They are an important and largely unrecognized component of the hydrogeochemistry and neotectonics of the southwestern United States.

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