Compared without electroless Ni–P alloy coating on the SiCp/Al composites, the paper describes the effect of Ni–P deposited layer on the microstructure evolution, shear strength, airtightness and fracture behavior of vacuum brazed joints. Void free and compact reaction layers along the 6063Al/Ni–P deposited layer/filler metal interfaces indicated that the joints exhibit high airtightness with He-leakage less than [Formula: see text] [Formula: see text]. Energy Dispersive X-ray Spectroscopy (EDS) analysis showed that the reaction layers mainly included brittle Al–Ni and Al–Cu–Ni intermetallics, where fracture occurred in priority and the shear strength was less than 90 MPa. However, without Ni–P alloy coating, sound joints with high shear strength of 100.1 MPa but low airtightness with He-leakage higher than [Formula: see text] were also obtained at 590[Formula: see text]C for soaking time of 30 min. In this case, a few holes that occurred along the filler metal/SiC particle interface significantly decreased the compactness of the joints. Therefore, according to the requirements in practical applications, suitable choice was provided in this research.
SiC particulate reinforced aluminum metal matrix composites (SiCp/Al MMCs) are characterized by controllable thermal expansion, high thermal conductivity and lightness. These properties, in fact, define the new promotional material in areas and industries such as the aerospace, automotive and electrocommunication industries. However, the poor weldability of this material becomes its key problem for large-scale applications. Sintering bonding technology was developed to join SiCp/Al MMCs. Cu nanoparticles and liquid Ga were employed as self-fluxing filler metal in air under joining temperatures ranging from 400 °C to 500 °C, with soaking time of 2 h and pressure of 3 MPa. The mechanical properties, microstructure and gas tightness of the joint were investigated. The microstructure analysis demonstrated that the joint was achieved by metallurgical bonding at contact interface, and the sintered layer was composed of polycrystals. The distribution of Ga was quite homogenous in both of sintered layer and joint area. The maximum level of joint shear strength of 56.2 MPa has been obtained at bonding temperature of 450 °C. The specimens sintering bonded in temperature range of 440 °C to 460 °C had qualified gas tightness during the service, which can remain 10−10 Pa·m3/s.
In this age of human civilization, there is a need for more efficient, cleaner, and renewable energy as opposed to that provided by nonrenewable sources such as coal and oil. In this sense, hydrogen energy has been proven to be a better choice. In this paper, a portable graphite crucible metal smelting furnace was used to prepare ten multi-element aluminum alloy ingots with different components. The microstructure and phase composition of the ingots and reaction products were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). The reaction was carried out in a constant temperature water bath furnace at 60 °C, and the hydrogen production performance of the multi-element aluminum alloys in different proportions was compared by the drainage gas collection method. The experimental results show that the as-cast microstructure of Al–Ga–In–Sn aluminum alloy is composed of a solid solution of Al and part of Ga, and a second phase of In3Sn. After the hydrolysis reaction, the products were dried at 150 °C and then analyzed by XRD. The products were mainly composed of AlOOH and In3Sn. Alloys with different compositions react at the same hydrolysis temperature, and the hydrogen production performance is related to the ratio of low-melting-point metal elements. By comparing two different ratios of Ga–In–Sn (GIS), the hydrogen production capacity and production rate when the ratio is 6:3:1 are generally higher than those when the ratio is 7:2:1. The second phase content affects the hydrogen production performance.
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