The GEOTRACES Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEls) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The IDP2014 covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The TEI data in the IDP2014 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at cross-over stations. The digital data are provided in several formats, including ASCII spreadsheet, Excel spreadsheet, netCDF, and Ocean Data View collection. In addition to the actual data values the IDP2014 also contains data quality flags and 1-sigma data error values where available. Quality flags and error values are useful for data filtering. Metadata about data originators, analytical methods and original publications related to the data are linked to the data in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2014 data providing section plots and a new kind of animated 3D scenes. The basin-wide 3D scenes allow for viewing of data from many cruises at the same time, thereby providing quick overviews of large-scale tracer distributions. In addition, the 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of observed tracer plumes, as well as for making inferences about controlling processes. (C) 2015 The Authors. Published by Elsevier B.V
We present new data for the stable isotope ratio of inorganic nitrogen species from the contrasting oxygen minimum zones (OMZs) of the Eastern Tropical North Atlantic, south of Cape Verde, and the Eastern Tropical South Pacific off Peru. Differences in minimum oxygen concentration and corresponding N-cycle processes for the two OMZs are reflected in strongly contrasting δ<sup>15</sup>N distributions. Pacific surface waters are marked by strongly positive values for δ<sup>15</sup>N-NO<sub>3</sub><sup>–</sup>) reflecting fractionation associated with subsurface N-loss and partial NO<sub>3</sub><sup>–</sup> utilization. This contrasts with negative values in NO<sub>3</sub><sup>–</sup> depleted surface waters of the Atlantic which are lower than can be explained by N supply via N<sub>2</sub> fixation. We suggest the negative values reflect inputs of nitrate, possibly transient, associated with deposition of Saharan dust. Strong signals of N-loss processes in the subsurface Pacific OMZ are evident in the isotope and N<sub>2</sub>O data, both of which are compatible with a contribution of canonical denitrification to overall N-loss. However the apparent N isotope fractionation factor observed is relatively low (ϵ<sub>d</sub>=11.4 ‰) suggesting an effect of influence from denitrification in sediments. Identical positive correlation of N<sub>2</sub>O vs. AOU for waters with oxygen concentrations ([O<sub>2</sub>] < 5 μmol l<sup>−1</sup>) in both regions reflect a nitrification source. Sharp decrease in N<sub>2</sub>O concentrations is observed in the Pacific OMZ due to denitrification under oxygen concentrations O<sub>2</sub> < 5 μmol l<sup>−1</sup>
We present a comparison of the dissolved stable isotope composition of silicate (δ30Si(OH)4) and nitrate (δ15 NO3−) to investigate the biogeochemical processes controlling nutrient cycling in the upwelling area off Peru, where one of the globally largest Oxygen Minimum Zones (OMZs) is located. Besides strong upwelling of nutrient rich waters mainly favoring diatom growth, an anticyclonic eddy influenced the study area. We observe a tight coupling between the silicon (Si) and nitrogen (N) cycles in the study area. Waters on the shelf showed high Si(OH)4 concentrations accompanied by diminished NO3− concentration as a consequence of intense remineralization, high Si fluxes from the shelf sediments, and N‐loss processes such as anammox/denitrification within the OMZ. Correspondingly, the surface waters show low δ30Si(OH)4 values (+2‰) due to low Si utilization but relatively high δ15 NO3− (+13‰) values due to upwelling of waters influenced by N‐loss processes. In contrast, as a consequence of the deepening of the thermocline in the eddy center, a pronounced Si(OH)4 depletion led to the highest δ30Si(OH)4 values (+3.7‰) accompanied by high δ15 NO3− values (+16‰). In the eddy center, high NO3−: Si(OH)4 ratios favored the growth of non‐siliceous organisms (Synechococcus). Our data show that upwelling processes and the presence of eddies play important roles controlling the nutrient cycles and therefore also exert a major influence on the phytoplankton communities in the Peruvian Upwelling. Our findings also show that the combined approach of δ30Si(OH)4 and δ15 NO3− can improve our understanding of paleo records as it can help to disentangle utilization and N‐loss processes.
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