Chemical shifts and full widths at half maximum intensity (FWHM) of K and K 1,3 x-ray emission lines and differences of full widths at half maximum intensity ( FHWM) using metallic element as reference for these emission lines were measured for oxygen compounds of elements in the range 22 Z 29 with a Wavelength-Dispersive X-Ray Fluorescence spectrometry (WDXRF). It was also found larger chemical shifts and FWHM for K 1,3 lines than those of K ones. It should be noted that the magnitude of chemical shifts increases with increase in the numbers of ligand atom.
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