The project consists in the implementation of a biocomposite based on tannin resin and natural rubber matrices with the bast fibres of Triumfetta cordifolia A.Rich. "Okong" from the equatorial region of Cameroon as reinforcement. A study of this still little known fibre is necessary. This paper evaluates the physico-chemical and mechanical characteristics of the fibers. The fibers are extracted by us. A series of experiments is conducted for this purpose: morphological observation with a scanning electron microscope (SEM); density evaluation with a helium pycnometer; absorption rate evaluation according to the protocol available in the literature, Fourier Transform Infrared Spectrometry (FT-IR), chemical composition evaluation according to ASTM 1972 and ASTM 1977 standards, thermogravimetric analysis (TGA) and tensile tests on fiber bundles according to NF T25-501-3. The results show that the fiber is made up of several elementary fibers with oval cross-sections. A density of 1.477 g/cm 3 close to that of hemp. These fibers have a water absorption rate of 342.5%, which correlates with the presence of free hydroxyl functional groups obtained from the spectrometry study (FT-IR). Chemical analysis reveals that the fiber is made up of celluloses (44.4%), hemicelluloses (30.8%), lignins (18.9%), pectins (3.3%), waxes (0.5%) and minerals (2.1%). In addition, we learn that the fibers studied dehydrate at 11.49%, showing a notable thermal stability around 235˚C with a peak thermal decomposition of
The influences of incorporating compatibilizers E-EA-MAH, E-MA-GMA, E-AM, SEBS KRATON G, or PP-g-MAH on the thermal properties of mixed (polypropylene/ethylene propylene rubber)/acrylonitrile butadiene styrene (PP/EPR)/ABS have been investigated. DSC investigations have revealed that the incorporation of 5% of ABS in the copolymer (PP/EPR) does not fundamentally affect the thermal properties of the basic copolymer; additionally, the addition of 1.5% of each of the compatibilizers in the basic mixture does not significantly alter the crystallization temperature values and the melting of the -P-sequences. There is a variation of melting enthalpy values of the -P-sequences of 18.23% using SEBS KRATON G and of 10.38% using E-AM-GMA. When the rate of each of the compatibilizers increases to 5%, overall crystallization enthalpies of -P-sequences are almost kept unchanged, except for the case of using the compatibilizer E-AM-GMA with a variation of 8.42%. There is a minor variation of the melting enthalpy of -P-sequences with higher levels of compatibilizer. The incorporation of 5% ABS copolymer in the PP/EPR does not significantly alter the thermal properties of the basic structure of (PP/EPR)/ABS.
This paper is aimed at identifying the risk factors that mainly contribute to reckless driving and other related causes of road accidents along the Douala-Dschang highway of Cameroon. The research work started with the collection of accident reports for 2018 and 2019 from security officials in charge of road safety and the police stations of the different localities included in the sample of the study. Three hundred and eighty-two (382) road accidents reports were collected and analyzed using the 2020 version logit regression model of XLSTAT. From these analyses, it appears that, of the 382 accidents recorded during this period, six factors were identified and classified as follows: causes of accidents related to speed and carelessness, location of the accident, type of vehicle at fault, day the accident occurred, time of the accident and the age of drivers involved. These results could contribute to reduce the gravity of accidents along the Douala-Dschang highway and develop other policies in the program for road safety. In addition, this study can as much as possible equally contribute to reorienting road construction trends and development techniques in our environment.
The objective of this paper is to investigate the relative variations of the constants of the thermal properties and the degree of crystallinity of the mixtures (PP/EPR)/Calcium carbonates elaborated with the Micro Bivis. We have strengthened the basic copolymer PP/EPR of a low level (5%) by three calcium carbonates models socal312, socal322v, Winnofil spm. We then subjected the different mixtures obtained, two cycles of a thermal loading under differential scanning calorimetry DSC. We finally focused on the thermal properties of isotactic polypropylene (T fP , T cP , ΔH fP , ΔH cP ) and we calculated the degree of crystallinity of the mixtures. Reducing the energy cost of implementing mixtures is one of the objectives of this work. We quantified the relative variations of the above properties with those of the base copolymer. It shows that at a low loading rate of calcium carbonate, there is a decrease in the enthalpies of crystallization during the second exothermic cycle, with values that can reach 5.53 J/g PP for the basic copolymer PP/EPR. During the second endothermic cycle, there is an overall increase in isotactic polypropylene melting temperature values for all the blends as well as for the basic copolymer PP/EPR. There is evidence that calcium carbonates are useful for lowering the melting energy of isotactic polypropylene, even at a low loading rate for the majority. The number of endothermic cycles accentuates this phenomenon which is linked to the presence in our composites, of a so-called confined amorphous phase.
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