No abstract

Phytoremediation is one of the environmental-friendly and cost-effective systems for the treatment of wastewater, including industrial wastewater such as palm oil mill effluent final discharge (POME FD). However, the effects of the wastewater on the phytoremediator plants, in term of growth performance, lignocellulosic composition, and the presence of nutrients and heavy metals in the plants are not yet well studied. In the present work, we demonstrated that POME FD increased the growth of P. purpureum. The height increment of P. purpureum supplied with POME FD (treatment) was 61.72% as compared to those supplied with rain water (control) which was 14.42%. For lignocellulosic composition, the cellulose percentages were 38.77 ± 0.29% (treatment) and 34.16 ± 1.01% (control), and the difference was significant. These results indicated that POME FD could be a source of plant nutrients, which P. purpureum can absorb for growth. It was also found that the heavy metals (Al, As, Cd, Co, Cr, Ni and Pb) inside the plant were below the standard limit of the World Health Organization (WHO). Since POME FD was shown to have no adverse effects on P. purpureum, further research regarding the potential application of P. purpureum following phytoremediation of POME FD such as biofuel production is warranted to evaluate its potential use to fit into the waste-to-wealth agenda. Pollution of soil and water caused by wastewater is one of the major global threats that our environment is facing today. One of the wastewater source is palm oil mill effluent final discharge (POME FD), which is a by-product of palm oil extraction process. Since Malaysia is the world's second largest producer and exporter of palm oil, thus, a large amount of POME is generate annually 1. It is estimated that for every tonne of crude palm oil produced, about 2.5 to 3.5 tonne of POME is generated 2. POME is considered as the main source of water pollution in Malaysia due to the high biochemical oxygen demand (BOD) and chemical oxygen demand (COD) that causes a reduction of the biodiversity and ability of aquatic ecosystem 3,4. Furthermore, the damages to the river cannot be undone easily. Since POME is generated in huge amounts at a time, it is very difficult to manage, and the treatment of this wastewater is expensive. Consequently, the cheapest and easiest way for this wastewater disposal that have been practiced in Malaysia is by discharging the treated POME to the nearby river or stream 2,5,6. However, Madaki and Seng 7 noted that even treated POME (POME FD) still poses adverse effects on the environment; an observation also supported by the findings of Ibrahim et al. 8. This is due to it still containing significant amount of organic matter. For that reasons, Ujang et al. 9 has decided to further treat the POME FD using Napier grass constructed wetland in a process called phytoremediation, and thus, achieved 71.57% of COD and 83.59% of total suspended solid (TSS) reduction. Phytoremediation is a process where plant naturally degrade, remove, or immobilize ...

The reason for such enormous efforts in palm oil mill effluent research would be what has been singled out as one of the major sources of pollution in Malaysia, and perhaps the most costly and complex waste to manage. Palm oil mill final discharge, which is the treated effluent, will usually be discharged to nearby land or river since it has been the least costly way to dispose of. Irrefutably, the quality level of the treated effluent does not always satisfy the surface water quality in conformity to physicochemical characteristics. To work on improving the treated effluent quality, a vertical surface-flow constructed wetland system was designed with Pennisetum purpureum (Napier grass) planted on the wetland floor. The system effectively reduced the level of chemical oxygen demand by 62.2 ± 14.3%, total suspended solid by 88.1 ± 13.3%, ammonia by 62.3 ± 24.8%, colour by 66.6 ± 13.19%, and tannin and lignin by 57.5 ± 22.3%. Heat map depicted bacterial diversity and relative abundance in life stages from the wetland soil, whereby bacterial community associated with the pollutant removal was found to be from the families Anaerolineaceae and Nitrosomonadaceae, and phyla Cyanobacteria and Acidobacteria.

Achieving a more sustainable wastewater treatment plant has never been so important. Issues around energy consumption and pollutants removal efficiency are of growing importance in the context of production costs and pollution control. In the palm oil industry, more than 85% mills are managing their palm oil mill effluent (POME) via lagoons, yet the system considered less effective as the quality of the effluent hardly achieved the permissible limits. It is therefore in the best interest of the industry to employ a better practice. Convective sludge drying (CSD) has been shown to have exceptional efficiency in high-strength wastewater treatment. In this study, CSD epitomized the zero-emission of POME treatment due to the fact that; 1) It operates on low-grade steam discharged by the mill instead of electricity, leading to a huge cut on energy consumption, 2) Production of secondary micronutrients-enriched solids by-product (i.e., calcium and magnesium) that can be repurposed as fertilizer, and 3) The decoction produced can potentially be reused to irrigate the existing oil palm plantation for nutrient cycling. The treatment resulted in substantial removal of the chemical oxygen demand (COD), biological oxygen demand (BOD), suspended solids (SS), ammoniacal nitrogen (AN), and oil and grease (OG) down to 2 mg/L, 67.7 mg/L, 40.0 mg/L, <0.01 mg/L, and <1 mg/L, respectively, which meets the Standard-A of Malaysia Environmental Quality Regulation (2009), making it sourceable for domestic usage. Reported groundworks demonstrated that CSD was superior to other physicochemical methods in POME treatment, with >99% of BOD, COD, SS, OG, and AN removal efficiency. The operating cost was valued at USD 1.91 per m3 POME. The pilot-scale operation proved CSD is a viable alternative to the lagoons.

Lignin is a natural biopolymer with a complex three-dimensional network and it is rich in phenol, making it a good candidate for the production of bio-based polyphenol material. This study attempts to characterize the properties of green phenol-formaldehyde (PF) resins produced through phenol substitution by the phenolated lignin (PL) and bio-oil (BO), extracted from oil palm empty fruit bunch black liquor. Mixtures of PF with varied substitution rates of PL and BO were prepared by heating a mixture of phenol–phenol substitute with 30 wt.% NaOH and 80% formaldehyde solution at 94 °C for 15 min. After that, the temperature was reduced to 80 °C before the remaining 20% formaldehyde solution was added. The reaction was carried out by heating the mixture to 94 °C once more, holding it for 25 min, and then rapidly lowering the temperature to 60 °C, to produce the PL−PF or BO−PF resins. The modified resins were then tested for pH, viscosity, solid content, FTIR, and TGA. Results revealed that the substitution of 5% PL into PF resins is enough to improve its physical properties. The PL−PF resin production process was also deemed environmentally beneficial, as it met 7 of the 8 Green Chemistry Principle evaluation criteria.