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ResumoO objetivo deste artigo é analisar a influência das fases presentes nas misturas iniciais e finais na eficiência de desfosforação do ferro-gusa. Foram realizados 8 experimentos no forno de resistência, na temperatura de 1400°C, e além disso foram feitas simulações no software FactSage 6.4. Como resultado, obteu-se que as misturas DP3 e DP4 são as mais eficientes, possuindo tanto na mistura inicial quanto na final saturação em CaO, ou seja, atividade do CaO igual a 1; atividade de FeO maior possível e maior quantidade de fase líquida possível. As misturas com fases sólidas DP5 a DP8 apresentaram menor eficiência de desfosforação, pode-se concluir então que as fases sólidas diminuem a eficiência de desfosforação em processos reais, apesar de reterem mais fósforo no equilíbrio. Palavras-chave: Desfosforação; Ferro-gusa; Termodinâmica computacional. INFLUENCE OF THE PHASES PRESENT IN THE INITIAL AND FINAL MIXES IN THE DEPHOSPHORIZATION EFFICIENCY OF HOT METAL AbstractThe main objective of this paper is to analyze the influence of the phases present in the initial and final mixes in the dephosphorization efficiency of hot metal. Eight experiments were carried out in a resistance furnace, with temperature of 1400 ° C, and moreover simulations were performed in FactSage 6.4 software . As a result, it was obtained that DP3 and DP4 mixtures are the most efficient, having both the initial and final mixture saturation upon CaO, that is CaO activity equal to 1; FeO activity longest and largest possible amount of liquid phase. Mixtures with the solid phases DP5 and DP8 showed lower dephosphorization efficiency, then it can be concluded that these phases decrease the dephosphorization efficiency in real cases, although retaining phosphorus in equilibrium balance.

Medication-related osteonecrosis of the jaw (MRONJ) is a debilitating complication associated with antiresorptive agents, in which treatment can be quite challenging. This study aimed to report two cases of cancer patients with MRONJ treated in a complementary manner by antimicrobial photodynamic therapy (aPDT). Both patients were male, 84 and 82 years old, respectively, and had a diagnosis of prostate adenocarcinoma and bone metastasis, treated with intravenous injections of bisphosphonates. The dental history for both was toothache, followed by extraction of dental elements that culminated with the appearance of necrotic bone in the mandibular region, which was confirmed with imaging exams and histopathological reports. The treatment protocol for both cases consisted of performing the aPDT once a week, associated with the use of 10 volumes hydrogen peroxide and 0.12% chlorhexidine digluconate for continuous use after oral brushing and amoxicillin with clavulanate three times a day for 7 days. The patient in case 1 performed 27 sessions, responded well to treatment, however, due to complications of the underlying neoplasm, he died without complete resolution of the osteonecrosis. In case 2, 32 sessions were carried out, with a good evolution of the symptoms. The patient is being followed up for 14 months, with no need for surgical intervention to date. Based on the reported cases and the literature survey, it can be concluded that aPDT can be an effective alternative in cases of MRONJ. The patients in the study in question showed success and control of the clinical picture.