With the help of quantum key distribution (QKD), two distant peers are able to share information-theoretically secure key bits. Increasing key rate is ultimately significant for the applications of QKD in lossy channel. However, it has proved that there is a fundamental rate-distance limit, named linear bound, which limits the performance of all existing repeaterless protocols and realizations. Surprisingly, a recently proposed protocol, called twinfield (TF) QKD can beat linear bound with no need of quantum repeaters. Here, we present the first implementation of TF-QKD protocol and demonstrate its advantage of beating linear bound at the channel distance of 300 km. In our experiment, a modified TF-QKD protocol which does not assume phase post-selection is considered, and thus higher key rate than the original one is expected. After well controlling the phase evolution of the twin fields travelling hundreds of kilometers of optical fibres, the implemented system achieves high-visibility single-photon interference, and allows stable and high-rate measurement-device-independent QKD.Our experimental demonstration and results confirm the feasibility of the TF-QKD protocol and its prominent superiority in long distance key distribution services.

Twin-field quantum key distribution(TF-QKD) protocol and its variants, such as phase-matching QKD, sending-or-not-sending QKD and no phase post-selection TF-QKD(NPP-TFQKD), are very promising for long-distance applications. However, there are still some gaps between theory and practice in these protocols. Concretely, a finite-key size analysis is still missing, and the intensity fluctuations are not taken into account. To address the finite-key size effect, we first give the key rate of NPP-TFQKD against collective attack in finite-key size region and then prove it can be against coherent attack. To deal with the intensity fluctuations, we present an analytical formula of 4-intensity decoy state NPP-TFQKD and a practical intensity fluctuation model. Finally, through detailed simulations, we show NPP-TFQKD can still keep its superiority of high key rate and long achievable distance.