Polydopamine-hemoglobin (PDA-Hb) microcapsules as suitable oxygen carriers are fabricated easily by templating decomposable MnCO3 particles in collaboration with self-polymerization of dopamine on pure Hb spheres. The PDA-Hb microcapsules possess a high oxygen affinity and are able to bind and release oxygen reversibly as demonstrated by electrochemical methods.

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Rechargeable Li–S batteries (LSBs) are emerging as an important alternative to lithium‐ion batteries (LIBs), owing to their high energy densities and low cost; yet sluggish redox kinetics of LiPSs results in inferior cycle life. Herein, we prepared multifunctional self‐supporting hyphae carbon nanobelt (HCNB) as hosts by carbonization of hyphae balls of Rhizopus, which could increase the S loading of the cathode without sacrificing reaction kinetics. Trace platinum (Pt) nanoparticles were introduced into HCNBs (PtHCNBs) by ion‐beam sputtering deposition. Based on the X‐ray photoelectron spectroscopy analyses, the introduced trace Pt regulated the local electronic states of heteroatoms in HCNBs. Electrochemical kinetics investigation combined with operando Raman measurements revealed the accelerated reaction mechanics of sulfur species. Benefiting from the synergistic catalytic effect and the unique structures, the as‐prepared PtHCNB/MWNCT/S cathodes delivered a stable capacity retention of 77% for 400 cycles at 0.5 C with a sulfur loading of 4.6 mg cm−2. More importantly, remarkable cycling performance was achieved with an high areal S loading of 7.6 mg cm−2. This finding offers a new strategy to prolong the cycle life of LSBs.

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Lithium–sulfur batteries (LBSs) have potential to become the future energy storage system, yet they are plagued by the sluggish redox kinetics. Therefore, enhancing the redox kinetics of polysulfide is a...