High confinement of surface plasmon polaritons in graphene at infrared frequencies enhances the light-matter interaction and can be used for the sensing of the environment. The considered sensing platform consists of parallel graphene ribbons which enables efficient coupling of an electromagnetic field into localized surface plasmons. Changes in the environment are then detected by measuring the resulting frequency shifts of the plasmonic resonances. It is shown that the graphene ribbons have the sensitivity comparable to the sensitivity of noble metal nanoparticles at visible frequencies, which enable sensing of only several nanometers thick films at wavelengths around ten microns. At the same time, the tunability of graphene plasmons enables a design of broadband substrates for surface enhanced infrared absorption of thin films. By changing the Fermi level in graphene, the plasmonic resonance of graphene ribbons can be adjusted to desired vibrational mode which facilitates detection of multiple absorption bands.
Engineering of a refractive index profile is a powerful method for controlling electromagnetic fields. In this paper, we investigate possible realization of isotropic gradient refractive index media at optical frequencies using two-dimensional graded photonic crystals. They consist of dielectric rods with spatially varying radii and can be homogenized in broad frequency range within the lowest band. Here they operate in metamaterial regime, that is, the graded photonic crystals are described with spatially varying effective refractive index so they can be regarded as low-loss and broadband graded dielectric metamaterials. Homogenization of graded photonic crystals is done with Maxwell-Garnett effective medium theory. Based on this theory, the analytical formulas are given for calculations of the rods radii which makes the implementation straightforward. The frequency range where homogenization is valid and where graded photonic crystal based devices work properly is discussed in detail. Numerical simulations of the graded photonic crystal based Luneburg lens and electromagnetic beam bend show that the homogenization based on Maxwell-Garnett theory gives very good results for implementation of devices intended to steer and focus electromagnetic fields.
Spectral and directional reshaping of fluorescence from dye molecules embedded in self-assembled hybrid plasmonic-photonic crystals has been examined. The hybrid crystals comprise two-dimensional hexagonal arrays of dye-doped dielectric nanospheres, capped with silver semishells. Comparing the reshaped fluorescence spectra with measured transmission/reflection spectra and numerical calculations reveals that the spectral and directional reshaping of fluorescence is the result of its coupling to photonic crystal Bloch modes and to void plasmons localized inside the silver caps.
Liquid-crystal devices are a promising cheap alternative for terahertz light modulation, albeit they suffer from problems associated with thick cells. Here we describe a few-micron-thick polarization-independent nematic liquid-crystal metamaterial device displaying terahertz reflectance modulation depths above 23 dB, millisecond response times, low operating voltages, and a spectral tuning of more than 15%. The dramatic performance improvement is based on invoking critical coupling with external fields, which rests on a suitable choice of resonator geometry. We analyze the coupling mechanism to conclude that perfect absorption can be reached with a wide range of parameters and liquid-crystal materials. The proposed device performance, microscopic details, and the nematic molecule switching dynamics are evaluated with the use of a rigorous tensorial formulation of the Landau-de Gennes theory and shown to be robust to small parameter deviations.
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