No abstract

No abstract

The corrosion of concrete structures by chloride salt is very significant in coastal environments. In order to improve the durability of marine concrete structures, cement-based materials with high durability need to be developed. In this investigation, the influence of NaCl freeze–thaw cycles (FT-C) and NaCl dry-wet alternations (DW-A) on the flexural and compressive strengths of reactive powder concrete (RPC) with an assembly unit of basalt fibers and steel fibers is studied. Additionally, the mass loss rate, the relative dynamic modulus of elasticity (RDEM), the chloride ion migration coefficient (CMC) and the impact toughness are measured after the NaCl FT-C and DW-A action. Our findings show that the RDEM, mass loss, and mechanical strength loss of RPC are increased by the ascending NaCl FT-C and DW-A. Meanwhile, the RDEM and the impact toughness are decreased by the NaCl FT-C and DW-A. The RPC with 0.5% basalt fibers and 1.5% steel fibers by volume of RPC shows the optimum mechanical performance and resistance to NaCl FT-C and DW-A. However, RPC with 3% steel fibers shows the worst resistance to NaCl erosion. The maximum mass loss rates, RDEM, flexural strength loss rate, compressive strength loss rate, CMC and impact toughness of all specimens after 300 NaCl FT-C and 30 NaCl DW-A are 4.5%, 91.7%, 28.1%, 29.3%, 3.2 × 10−12 (m2/s) and 2471 J. Meanwhile, the corresponding minimum values are 1.62%, 83.2%, 20.4%, 15.7%, 1.1 × 10−12 (m2/s) and 625 J. The researching findings will provide an optimum mix ratio of RPC with an assembly unit of basalt fibers and steel fibers, which can be applied in the marine engineering environment.

The ownership of the research reported in the article 'Lightabsorption enhancement design of ultrathin perovskite solar cells with conformal structure' has been brought into question and, upon the request of the authors, IOP Publishing has agreed to retract the work. The institution concerned has been notified in order that an internal investigation can be conducted.

Based on the first-principles method, the structural stability and the contribution of point defects such as O, Sr or Ti vacancies on two-dimensional electron gas of n- and p-type LaAlO3/SrTiO3 interfaces are investigated. The results show that O vacancies at p-type interfaces have much lower formation energies, and Sr or Ti vacancies at n-type interfaces are more stable than the ones at p-type interfaces under O-rich conditions. The calculated densities of states indicate that O vacancies act as donors and give a significant compensation to hole carriers, resulting in insulating behavior at p-type interfaces. In contrast, Sr or Ti vacancies tend to trap electrons and behave as acceptors. Sr vacancies are the most stable defects at high oxygen partial pressures, and the Sr vacancies rather than Ti vacancies are responsible for the insulator-metal transition of n-type interface. The calculated results can be helpful to understand the tuned electronic properties of LaAlO3/SrTiO3 heterointerfaces.