Acyclovir is an antiviral effective drug active compound. A glassy carbon electrode (GCE) was modified with an electropolymerized film of p‐aminobenzene sulfonic acid (p‐ABSA) in phosphate buffer solution (PBS). The polymer film‐modified electrode was used to electrochemically detect acyclovir. Polymer film showed excellent electrocatalytic activity for the oxidation of acyclovir. The anodic peak potential value of the acyclovir at the poly(p‐ABSA) modified glassy carbon electrode was 950 mV obtained by DPV. A linear calibration curve for DPV analysis was constructed in the acyclovir concentration range 2×10−7–9×10−6 mol L−1. Limit of detection (LOD) and limit of quantification (LOQ) were obtained as 5.57×10−8 and 1.85×10−7 mol L−1 respectively. The proposed method exhibits good recovery and reproducibility.
In this study, the electrochemical reduction and determination of metronidazole were easily realized in Britton-Robinson buffer (pH = 4.01) using UTGE by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. In this acidic medium, one irreversible and sharp cathodic peak was observed. A linear calibration curve for DPV analysis was constructed in the metronidazole concentration range 3x10-6 - 9x 10-5 mol L-1. Limit of detection (LOD) and limit of quantification (LOQ) were 1.42x10-7 and 4.76x10-7 mol L-1 respectively
Heavy
metals are an important pollutant group. Adsorption is one
of the methods used to remove heavy metals from the environment. Mosses
were preferred as bio-indicators because they have the capacity to
accumulate many elements by their high surface-to-volume ratio. Leucodon sciuroides (Hedw.) Schwägr. (LS)
are mosses that play an important part of the ecosystem and are collected
from the Ida Mountain (Kazdag) region of Çanakkale (Turkey).
For the purpose of determining the adsorption capacity of heavy metal
ion (Pb2+, Cd2+, Co2+, Ni2+, Zn2+, and Cu2+) analysis conditions, pH,
contact time, and adsorbent amounts were determined and the maximum
adsorption capacity was calculated with the help of the relevant isotherms.
Heavy metal concentrations were determined by inductively coupled
plasma-mass spectrometry. It was determined that the optimum adsorption
for mosses was 30 min at pH = 6.0 (the pH at which maximum adsorption
occurs). The adsorption event shows that some divalent cations fit
the Freundlich isotherm and some fit the Langmuir isotherm model.
A pseudo-second-order reaction best fits the kinetic data for metal
ions. Among the six metal ions studied, the highest adsorption was
observed in Pb2+ and Cu2+ cations. According
to the competitive adsorption results, the moss has a great advantage
in determining the Pb2+ and Cu2+ cations industrially
as well as other metals and in removing other metal impurities from
the environment. Also, LS is exploited as a biosorbent to remove metal
ions from aqueous solutions and can be used as a biomarker.
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