Inorganic
perovskite quantum dots (PQDs) have emerged as an unprecedented
class of optoelectronic materials due to their notable properties.
However, their inherent poor stability has become the main impediment
restricting the broad applications of PQDs. Herein, with the aim to
enhance the stability of PQDs, we developed a photocatalytic polymerization
strategy to encapsulate CsPbBr3 PQDs into a polyaniline
(PANI) polymer matrix. The resultant CsPbBr3/PANI composite
showed exceptional water stability, with its structure and morphology
remaining unchanged even after being immersed in water for 4 weeks.
Furthermore, the CsPbBr3/PANI composite could maintain
approximately 93% of its original photoluminescence (PL) intensity
after 4 weeks, while that of pristine CsPbBr3 was fully
quenched along with structure degradation. More impressively, the
CsPbBr3/PANI composite exhibited improved charge transport
properties due to the electrical conductivity of the PANI protective
layer, leading to enhanced photoelectrochemical activity in water.
This work provides some insights into the rational design of PQDs
with high stability and photoelectric properties for optoelectronic
and photocatalytic applications.
Soft materials with self-assembled networks possess saddle-shaped interfaces with distributed negative Gaussian curvatures. The ability to stabilize such a geometry is critically important for various applications but can be challenging due to the possibly "deficient" packing of the building blocks. This nontrivial challenge has been manifested, for example, by the limited availability of crosslinkable bicontinuous cubic (Q) liquid crystals (LCs), which can be utilized to fabricate compelling polymers with networked nanochannels uniformly sized at ∼1 nm. Here, we devise a facile approach to stabilizing cross-linkable Q mesophases by leveraging the synergistic self-assembly from pairs of scalably synthesized polymerizable amphiphiles. Hybridization of the molecular geometries by mixing significantly increases the propensity of the local deviations in the interfacial curvature specifically required for Q assemblies. "Normal" (type 1) double gyroid LCs possessing 1 nm ionic channels conforming to minimal surfaces can be formulated by simultaneous hydration of the amphiphile mixtures, as opposed to the formation of hexagonal or lamellar mesophases exhibited by the single-amphiphile systems, respectively. Fixation of the bicontinuous network in polymers via radical polymerization has been efficaciously facilitated by the presence of the bifunctional polymerizable groups in one of the employed amphiphiles. High-fidelity lock-in of the ordered continuous 1 nm channels has been unambiguously confirmed by the observation of single-crystal-like diffraction patterns from synchrotron small-angle X-ray scattering and large-area periodicities by transmission electron microscopy. The produced polymeric materials exhibit the required mechanical integrity as well as chemical robustness in a variety of organic solvents that benefit their practical applications for selective transport of ions and molecules.
Internet accessibility for older users has become an important issue to promote inclusion and participation in the Information Society. This paper proposes an investigation into the technology accessibility problems faced by older users in China. The research reported here was conducted by means of an exploratory survey with a Web-based questionnaire and discussions with older users at meetings. The study had 180 valid answers and involved representatives from each of the 25 provinces of China. The results show that 39% of the participants cannot or can only partially access information, because of various kinds of accessibility problems. Many participants indicated that the main problems in accessing the Internet were health barriers, circumstances barriers, and Internet design barrier. The possible reason for these difficulties could be that the government doesn't foster a social environment conducive to helping the elderly to get online and that it does not provide services for the elderly designed to help them access information electronically. The poor rate of accessibility industry for the elderly, as well as the lack of Chinese accessibility laws, is an important issue that must be dealt with to promote greater Internet accessibility for the elderly.
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