Metasurfaces offered great opportunities to control electromagnetic (EM) waves, but currently available meta-devices typically work either in pure reflection or pure transmission mode, leaving half of EM space completely unexplored. Here, we propose a new type of metasurface, composed by specifically designed meta-atoms with polarization-dependent transmission and reflection properties, to efficiently manipulate EM waves in the full space. As a proof of concept, three microwave meta-devices are designed, fabricated and experimentally characterized. The first two can bend or focus EM waves at different sides (i.e., transmission/reflection sides) of the metasurfaces depending on the incident polarization, while the third one changes from a wave bender for reflected wave to a focusing lens for transmitted wave as the excitation polarization is rotated, with all these functionalities exhibiting very high efficiencies (in the range of 85%-91%) and total thickness ~/8  . Our findings significantly expand the capabilities of metasurfaces in controlling EM waves, and can stimulate high-performance multi-functional meta-devices facing more challenging and diversified application demands.

As a result of inherent rigidity of the conjugated macromolecular chains resulted from the delocalized π-electron system along the polymer backbone, it has been a huge challenge to make conducting polymer hydrogels elastic by far. Herein elastic and conductive polypyrrole hydrogels with only conducting polymer as the continuous phase have been simply synthesized in the indispensable conditions of 1) mixed solvent, 2) deficient oxidant, and 3) monthly secondary growth. The elastic mechanism and oxidative polymerization mechanism on the resulting PPy hydrogels have been discussed. The resulting hydrogels show some novel properties, e.g., shape memory elasticity, fast functionalization with various guest objects, and fast removal of organic infectants from aqueous solutions, all of which cannot be observed from traditional non-elastic conducting polymer counterparts. What's more, light-weight, elastic, and conductive organic sponges with excellent stress-sensing behavior have been successfully achieved via using the resulting polypyrrole hydrogels as precursors.

A thin screen exhibiting dynamically switchable transmission/absorption functionalities is highly desired in practice. However, a trilayer transmissive metasurface with active elements controlled in a uniform manner cannot exhibit independently controlled transmission and absorption properties due to intriguing interplays between the scattering and absorbing properties in systems exhibiting inversion symmetries. This motivates to employ the coupled‐mode theory to establish a generic phase diagram for such transmissive metasurfaces with active elements loaded in different layers tuned independently and to guide researchers design tunable metadevices with completely decoupled transmission/absorption responses. Based on such a phase diagram, a microwave metasurface is designed/fabricated with PIN diodes incorporated, and it is experimentally demonstrated that its functionality can switch from perfect transparency to perfect absorption, controlled by external voltages applied across the diodes. In addition to finding immediate applications in practice (e.g., smart radomes), the results of this study also provide a new type of tunable meta‐atom for building metasurfaces with flexible wave‐front control abilities.

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