Gallium nitride (GaN) light-emitting-diode (LED) technology has been the revolution in modern lighting. In the last decade, a huge global market of efficient, long-lasting, and ubiquitous white light sources has developed around the inception of the Nobel-prize-winning blue GaN LEDs. Today, GaN optoelectronics is developing beyond solid-state lighting, leading to new and innovative devices, e.g., for microdisplays, being the core technology for future augmented reality and visualization, as well as point light sources for optical excitation in communications, imaging, and sensing. This explosion of applications is driven by two main directions: the ability to produce very small GaN LEDs (micro-LEDs and nano-LEDs) with high efficiency and across large areas, in combination with the possibility to merge optoelectronic-grade GaN micro-LEDs with silicon microelectronics in a hybrid approach. GaN LED technology is now even spreading into the realm of display technology, which has been occupied by organic LEDs and liquid crystal displays for decades. In this review, the technological transition toward GaN micro- and nanodevices beyond lighting is discussed including an up-to-date overview on the state of the art.
The demonstration of vertical GaN wrap-around gated field-effect transistors using GaN nanowires is reported. The nanowires with smooth a-plane sidewalls have hexagonal geometry made by top-down etching. A 7-nanowire transistor exhibits enhancement mode operation with threshold voltage of 1.2 V, on/off current ratio as high as 108, and subthreshold slope as small as 68 mV/dec. Although there is space charge limited current behavior at small source-drain voltages (Vds), the drain current (Id) and transconductance (gm) reach up to 314 mA/mm and 125 mS/mm, respectively, when normalized with hexagonal nanowire circumference. The measured breakdown voltage is around 140 V. This vertical approach provides a way to next-generation GaN-based power devices.
A film of gas sensitive ZnO nanoparticles has been coupled with a low-power micro light plate (μLP) to achieve a NO 2 -parts-per-billion conductometric gas sensor operating at room temperature. In this μLP configuration, an InGaN-based LED (emitting at 455 nm) is integrated at a few hundred nanometers distance from the sensor material, leading to sensor photoactivation with well controlled, uniform, and high irradiance conditions, and very low electrical power needs. The response curves to different NO 2 concentrations as a function of the irradiance displayed a bell-like shape. Responses of 20% to 25 ppb of NO 2 were already observed at irradiances of 5 mWatts•cm −2 (applying an electrical power as low as 30 μW). In the optimum illumination conditions (around 60 mWatts•cm −2 , or 200 μW of electric power), responses of 94% to 25 ppb were achieved, corresponding to a lower detection limit of 1 ppb of NO 2 . Higher irradiance values worsened the sensor response in the partsper-billion range of NO 2 concentrations. The responses to other gases such as NH 3 , CO, and CH 4 were much smaller, showing a certain selectivity toward NO 2 . The effects of humidity on the sensor response are also discussed. KEYWORDS: gas sensor, nitrogen dioxide (NO 2 ), high sensitivity, photo/light activation, micro light plate (μLP), light emitting diode (LED),
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