We report on the electrical conductivity s of a series of nominally uncompensated neutrontransmutation-doped isotopically enriched 70 Ge:Ga samples with the Ga concentration [Ga] near N c for the metal-insulator transition. s of all insulating samples obeys ln s~2͑T 0 ͞T͒ 1͞2 with T 0~͑ N c -͓Ga͔͒͞N c while the zero temperature conductivity s͑0͒ of the metallic samples is s͑0͕͒ ͓͑Ga͔-N c ͒͞N c ͖ n with the critical exponent n ഠ 0.5. The values of N c obtained from the two independent scalings of T 0 and s͑0͒ are identical, i.e., n ഠ 0.5 is established unambiguously for uncompensated Ge:Ga. [S0031-9007(96)01533-5] PACS numbers: 71.30.+h, 72.80.Cw In experimental studies of the metal-insulator (MI) transition one measures the critical behavior of physical quantities such as conductivity, dielectric constant, heat capacity, etc. The doping induced MI transition in semiconductors is considered to be a model case for the general theory of the critical behaviors of solids. In particular the conductivity extrapolated to zero temperature ͓s͑0͔͒ is evaluated routinely as a function of doping concentration (N) immediately above the MI transition critical concentration ͑N c ͒;where s 0 is the prefactor and n is the critical exponent. The value of n, determined experimentally, is compared with theoretical predictions. Up to now n ഠ 0.5 has been obtained with nominally uncompensated semiconductors (Si:P [1], Si:As [2,3], Ge:As [4], Si:B [5]) while n ഠ 1 has been found with compensated semiconductors (Ge:Sb [6], Si:P,B [7], Ge:Ga,As [8]) and amorphous alloys [9-12]. Exceptions are uncompensated Ge:Sb with n ഠ 1 [13] and Ga x Ar 12x amorphous alloys with n ഠ 0.5 [14]. As we explain below, the value of n ഠ 0.5 obtained with simple systems like uncompensated semiconductors turns out to be inconsistent with theoretical predictions [15]. In his original theory Mott considered only the electron-electron ͑e 2 -e 2 ͒ interaction (Mott transition) and predicted a discontinuous transition of s͑0͒ at N c [16]. Although there is much evidence for the importance of e 2 -e 2 interactions, no experimental observation of such an abrupt transition has been reported. Anderson's idea of MI transitions is based solely on the disordered potential arising from randomly distributed dopants (Anderson transition) [17]. This lead to the development of the well-known "scaling theory" which predicted n ഠ 1 for three dimensional systems [18]. More recently, higher order calculations of the scaling theory (exclusively with disorder and no interactions) predict n ഠ 1.3 [19], and, more importantly, this value is shown to be independent of time reversal invariance [20] and of the strength of spin-orbit interactions [21]. It is therefore clear that the effect of disorder alone cannot explain the experimental results of n ഠ 0.5 or 1. Chayes et al. combined the theories of Mott and Anderson and successfully set the lowest limit n . 2͞3 [22]. This result permits n ഠ 1 obtained with compensated semiconductors and amorphous alloys. However, there still is no th...
Publication costs assisted by Keio University Absorption spectra of rhodamine B are examined in solutions of glycerol, ethylene glycol, and acetic acid. Particular attention is given to the absorption spectra of monomers and dimers of rhodamine B in these solutions. Furthermore, dimeric structures of rhodamine B in these solutions are also investigated.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.