An intense cold-atom beam source based on a modified pyramidal magneto-optical trap has been developed and characterized. We have produced a slow beam of cold cesium atoms with a continuous flux of 2.2 ϫ 10 9 atoms/s at a mean velocity of 15 m/s and with a divergence of 15 mrad. The corresponding radiant intensity is 1.2 ϫ 10 13 atom s Ϫ1 sr Ϫ1 . We have characterized the performance of our beam source over a range of operating conditions, and the measured values for atom flux, mean velocity, and divergence are in good agreement with results from detailed Monte Carlo numerical simulations.

The photodissociation of vinyl iodide has been investigated at several wavelengths between 193 and 266 nm using three techniques: time-resolved Fourier transform emission spectroscopy, multiple pass laser absorption spectroscopy, and velocity-mapped ion imaging. The only dissociation channel observed is C-I bond cleavage to produce C2H3 (nu, N) + I (2P(J)) at all wavelengths investigated. Unlike photodissociation of other vinyl halides (C2H3X, X = F, Cl, Br), in which the HX product channel is significant, no HI elimination is observed. The angular and translational energy distributions of I atoms indicate that atomic products arise solely from dissociation on excited states with negligible contribution from internal conversion to the ground state. We derive an upper limit on the C-I bond strength of D0(C2H3-I) < or = 65 kcal mol(-1). The ground-state potential-energy surface of vinyl iodide is explored by ab initio calculations. We present a model in which the highest occupied molecular orbital in vinyl halides has increasing X(np) non-bonding character with increasing halogen mass. This change leads to reduced torsional force around the C-C bond in the excited state. Because the ground-state energy is highest when the CH2 plane is perpendicular to the CHX plane, a reduced torsional force in the excited state correlates with a lower rate for internal conversion compared to excited-state C-X bond fission. This model explains the gradual change in photodissociation mechanisms of vinyl halides from the dominance of internal conversion in vinyl fluoride to the dominance of excited-state dissociation in vinyl iodide.

We present an experimental apparatus that produces Bose-Einstein condensates (BECs) of 87 Rb atoms at a rate of 1 Hz. As a demonstration of the system's ability to operate continuously, 30 BECs were produced and imaged in 32.1 s. Without imaging, a single BEC could be produced in 953 ms. The system uses an atom chip to confine atoms in a dimple trap with frequencies exceeding 1 kHz. With this tight trap, the duration of evaporative cooling can be reduced to less than 0.5 s. Using principal component analysis, insight into the largest sources of noise and drift was obtained by extracting the dominant contributions to the variance. The system utilizes a compact physics package that can be integrated with lasers and electronics to create a transportable ultracold-atom device for applications outside of a laboratory environment.

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An atom-chip-based integrated optical lattice system for cold and ultracold atom applications is presented. The retroreflection optics necessary for forming the lattice are bonded directly to the atom chip, enabling a compact and robust on-chip optical lattice system. After achieving Bose-Einstein condensation in a magnetic chip trap, we load atoms directly into a vertically oriented 1D optical lattice and demonstrate Landau-Zener tunneling. The atom chip technology presented here can be readily extended to higher dimensional optical lattices.