This objective of this article is to present a new technique of nanofluids/MQL in high speed milling by using MWCNTs. In the past, studies have shown the MQL process can improve tool life and surface accuracy in high speed cutting. The purpose of using carbon nanotubes is to increase the thermal conductivity of cutting fluid and to reduce the temperature during the cutting and decrease the thermal wear of tool. The proposed study is to investigate the characterization of the MWCNTs/ nanofluids combined with MQL during the high speed milling of AISI 1050 and AISI P21 experimentally. The Taguchi robust design was also used to optimize the parameters of nozzle with respect to tool feed direction, such as spraying distance, angle of ejection, and relative locations for improving the MWCNTs/MQL cutting effect. Experimental results showed the MWCNTs/ nanofluid had the benefits of improving surface roughness and reducing wear of tool in high speed milling. The results were compared to dry cutting, and wet cutting in detail.
A quantitative structure-activity relationship (QSAR) study for predicting the acute toxicity 96h - LC50 values of substituted anilines and phenols to carp is presented in this work. For this, the descriptors were obtained with DFT method at the B3LYP/6-311G** level using the Gaussian 03 software package. Afterwards the obtained parameters were taken as theoretical descriptors to establish a QSAR model for predicting -lgLC50. The model contains two variables, energy of the highest occupied molecular orbital (EHOMO) and energy of the lowest unoccupied molecular orbital (ELUMO), which suggest that the main effect on biological toxicity of phenols and anilines is the interaction of electrons between the molecules of organic chemicals. Besides, the model was further validated by variance inflation factors (VIF) and t-test, and show fine stabilities and predictive abilities, which can be used to predict -lgLC50 of these kinds of compounds.
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