Developing degradable filter membranes that inhibit bacterial infection for preventing particle matter and infectious disease has been a research hotspot. Here, the fiber membranes of polylactic acid (PLA)/HKUST-1 with porous structure through the entire fiber matrix were prepared by electrospinning method. Due to the HKUST-1 incorporation and the presence of pore through fiber, the hydrophobicity of prepared membranes had been improved. The PLA/HKUST-1 membranes exhibited the good antibacterial activity against Escherichia coli and Staphylococcus aureus, and the antibacterial rate for S. aureus reached 99.99%. The filtration performance of PLA/HKUST-1 membranes was better than that of the melt-blown fabric although their thickness was only about one-third of the thickness of the currently commercial polypropylene melt-blown fabric.
Nano (Fe)MIL-101 particles were grafted on the short carbon fibers (SCFs) by in situ growth method to prepare (Fe)MIL-101@SCFs. The flame-retarded composites of epoxy resin (EP) were fabricated with combination of (Fe)MIL-101@SCFs and ammonium polyphosphate (APP). The composites showed good flame retardancy, smoke suppression, and mechanical properties simultaneously. The main heat release rate peak of the flame-retarded composites was reduced and delayed evidently in comparison with pristine EP. The high amount of residual char with coherent and dense structure was formed owing to the catalytic char formation of (Fe)MIL-101 as well as the strengthening action of SCF. The improvement in mechanical properties of the flame-retarded composite was due to the reinforcement effects of (Fe)MIL-101@SCFs and its action of interfacial adjustment. This research solved the contradiction between the flame retardancy and mechanical properties of EP, and proposed a new method to prepare the mechanically reinforced and flame retardant EP.
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